Lithium acetate dihydrate

Base Information

• Chemical Name: Lithium acetate dihydrate
• CAS No.: 6108-17-4
• Molecular Formula: C₂H₃O₂*2H₂O*Li
• Molecular Weight: 102.016
• Hs Code.: 29152990
• Mol file: 6108-17-4.mol

Synonyms:Lithiumacetate dihydrate;Acetic acid lithium salt dihydrate;

Chemical Property of Lithium acetate dihydrate

Chemical Property:

• Appearance/Colour: White rhombohedral crystals
• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: 53-56 °C(lit.)
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 58.59000
• Density: 1,3 g/cm3
• LogP: -1.37240
• Storage Temp.: −20°C
• Solubility.: H2O: 1 M at 20 °C, clear, colorless
• Water Solubility.: 29 g/100 mL (20 ºC)

Purity/Quality:

99% ^*data from raw suppliers

Lithium acetate dihydrate, 98% (99.9%-Li) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi; Xn
• Hazard Codes: Xi,Xn
• Statements: 36-63-20/21/22
• Safety Statements: 22-24/25-39-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Lithium acetate dihydrate is used as a buffer component in the modified ninhydrin reagent for amino analysis by ion-exchange chromatography. It is used as a catalyst in organic reactions, alkyd resin and acrylic polymer production and as an anticorrosion agent in molding polyphenylene sulfide resins as well as in the separation of saturated and unsaturated fatty acids. In the pharmaceutical industry, it is utilized for the preparation of diuretics. Lithium acetate dihydrate has been used for yeast transformation.

Technology Process of Lithium acetate dihydrate

There total 2 articles about Lithium acetate dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium carbonate (554-13-2) + acetic acid (64-19-7,77671-22-8) → lithium acetate dihydrate (6108-17-4,61013-21-6,61013-23-8,67299-15-4,116277-84-0)

Guidance literature:

In acetic acid; vaporization of soln. of Li2CO3 in acetic acid;;

Reference yield:

lithium nitrate + acetic anhydride (108-24-7) → lithium acetate dihydrate (6108-17-4,61013-21-6,61013-23-8,67299-15-4,116277-84-0)

Guidance literature:

In acetic anhydride; solving LiNO3 in actic anhydride;;

Reference yield: 89.0%

lithium acetate dihydrate (6108-17-4,61013-21-6,61013-23-8,67299-15-4,116277-84-0) + cyclohexa-1,3-diene (1165952-91-9) → cis-1-acetoxy-4-chlorocyclohex-2-ene (82736-39-8)

Guidance literature:

With p-benzoquinone; lithium chloride; palladium diacetate; In acetic acid; for 8h; Ambient temperature;

DOI:10.1016/S0040-4039(00)87173-7

upstream raw materials:

lithium carbonate

acetic acid

acetic anhydride

Downstream raw materials:

cis-1-acetoxy-4-chlorocyclohex-2-ene

(2R,5R)-2-Butyl-5-propyl-1-(toluene-4-sulfonyl)-pyrrolidine

trans-N-(p-tolylsulfonyl)-2-butyl-5-propylpyrrolidine

trans-N-(p-tolylsulfonyl)-2-heptyl-5-butylpyrrolidine

Refernces