NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆

Base Information

• Chemical Name: NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆
• CAS No.: 18535-07-4
• Molecular Formula: AsF₆*NO
• Molecular Weight: 218.918
• Mol file: 18535-07-4.mol

Synonyms:NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆

Chemical Property of NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆

There total 3 articles about NO⁽¹⁺⁾*AsF₆^(1-)=NOAsF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ONClF(1+)*AsF6(1-) = ONClF(AsF6) (133129-78-9) → NO(1+)*AsF6(1-)=NOAsF6 (18535-07-4) + chlorine monofluoride (7790-89-8)

Guidance literature:

In trichlorofluoromethane; at -78°C; reaction of ClF with reaction glass vessel to SiF4;

Reference yield:

arsenic(III) fluoride (7784-35-2) + nitrosyl fluoride (7789-25-5) → NO(1+)*AsF6(1-)=NOAsF6 (18535-07-4) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In neat (no solvent);

Reference yield:

N2F(1+)*AsF6(1-) = (N2F)AsF6 (12005-87-7) + nitrosyl fluoride (7789-25-5) → NO(1+)*AsF6(1-)=NOAsF6 (18535-07-4) + cis-difluorodiazene (13812-43-6)

Guidance literature:

In neat (no solvent); addn. of FNO at -196°C, allowed to warm to -78°C, allowed to warm to room temp. over a period of 12 h; cooled to -196°C, sepn. by fractional condensation;

DOI:10.1021/ja00010a023

upstream raw materials:

arsenic(III) fluoride

nitrosyl fluoride

N₂F⁽¹⁺⁾*AsF₆^(1-) = (N₂F)AsF₆

ONClF⁽¹⁺⁾*AsF₆^(1-) = ONClF(AsF₆)

Downstream raw materials:

arsenic pentafluoride

Refernces

• 1、 Minkwitz, Rolf,Bernstein, Dirk,Preut, Hans,Sartori, Peter. "Preparation of the nitryl salts ON(Cl)F+AsF6-, ON(CF3)F+AsF6-, and HON(CH2)CF3+SbF6- and crystal structure of HON(CH2)CF3+AsF6-". . p. 2157 - 2161. Retrieved 2008/10/08.