6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

Base Information

Chemical Name:6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde
CAS No.:70057-97-5
Molecular Formula:C₈H₁₂O₅
Molecular Weight:188.18
Hs Code.:

Synonyms:6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

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Chemical Property of 6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

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Technology Process of 6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

There total 2 articles about 6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 10368-86-2
1,2:5,6-di-O-isopropylidene-α-D-galactofuranose

: 70057-97-5
6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: With sodium periodate; periodic acid; In ethyl acetate; at 20 ℃; for 5h;
DOI:10.1016/S0040-4020(02)00230-2

Reference yield:

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 70057-97-5
6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

Guidance literature:: With periodic acid; In ethyl acetate; at 20 ℃; for 20h;
DOI:10.1016/j.tet.2015.05.040

Reference yield:

: 100-58-3
phenylmagnesium bromide

: 70057-97-5
6-hydroxy-2,2-dimethyl-(3aR,5R,6S,6aR)-perhydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

: 18439-35-5
(3aR,5R,6S,6aR)-5-((R)-hydroxy(phenyl)methyl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole-6-ol

: 18439-34-4
(3aR,5R,6S,6aR)-5-((S)-hydroxy(phenyl)methyl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole-6-ol

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; toluene; at 0 - 20 ℃; for 76h; stereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2015.05.040