2,4,6-Tris[o-(bromomethyl)phenyl]boroxine

Base Information

• Chemical Name: 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine
• CAS No.: 7481-16-5
• Molecular Formula: C₂₁H₁₈B₃Br₃O₃
• Molecular Weight: 590.517
• Mol file: 7481-16-5.mol

Synonyms:2,4,6-Tris[o-(bromomethyl)phenyl]boroxine

Chemical Property of 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine

There total 8 articles about 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tri-o-tolylboroxine (7294-50-0) + bromine (7726-95-6) → 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine (7481-16-5)

Guidance literature:

With dibenzoyl peroxide; In tetrachloromethane; other Radiation; irradiation for 20min;;

DOI:10.1021/jo01278a018

Reference yield:

N-Bromosuccinimide (128-08-5) + bromine (7726-95-6) → 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine (7481-16-5)

Guidance literature:

With dibenzoyl peroxide; In tetrachloromethane; other Radiation;

DOI:10.1021/ja01500a019 DOI:10.1021/ja01547a033

Reference yield:

ortho-tolylmagnesium bromide (932-31-0) → 2,4,6-Tris[o-(bromomethyl)phenyl]boroxine (7481-16-5)

Guidance literature:

Multi-step reaction with 3 steps

1: diethyl ether

2: (dehydration)

3: (bromination)

In diethyl ether;

DOI:10.1021/ja01500a019

upstream raw materials:

tri-o-tolylboroxine

ortho-tolylmagnesium bromide

2-Methylphenylboronic acid

N-Bromosuccinimide

Downstream raw materials:

2,4,6-tris[2-(N,N-dimethylaminomethyl)phenyl]boroxin

5-butyl-2⁶-[2-(butylamino-methyl)-phenyl]-5-aza-1,3(1,2)-dibenzena-2(2,4)-cyclotriboroxana-cyclohexaphane

(2-(C₆H₁₁)2NCH₂-C₆H₄)B(OH)2

C₁₉H₃₃BN₂O₆