(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

Base Information

Chemical Name:(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol
CAS No.:1070800-59-7
Molecular Formula:C₃₄H₄₃Cl₃O₈
Molecular Weight:686.07
Hs Code.:

(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

Synonyms:(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

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Chemical Property of (1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

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Technology Process of (1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

There total 1 articles about (1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1070800-44-0
3-benzyloxymethoxy-2-vinylbenzaldehyde

: 1070800-58-6
(2S,3R)-2-[(1S,2S)-2-methoxy-1-(2,2,2-trichloroethoxymethoxy)penta-3,4-dienyl]-3-methyl-1,4-dioxaspiro[4.4]nonane

: 1070800-59-7
(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

Guidance literature:: (2S,3R)-2-[(1S,2S)-2-methoxy-1-(2,2,2-trichloroethoxymethoxy)penta-3,4-dienyl]-3-methyl-1,4-dioxaspiro[4.4]nonane; With diisopinocampheylborane; In diethyl ether; at 23 ℃; for 0.25h; Inert atmosphere;

3-benzyloxymethoxy-2-vinylbenzaldehyde; In diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere;

With methanol; In diethyl ether; at -78 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ol8018727

Reference yield: 86.0%

: 75-15-0,12122-00-8
carbon disulfide

: 1070800-59-7
(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

: 74-88-4
methyl iodide

: 1070800-64-4
dithiocarbonic acid {(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-enyl} ester methyl ester

Guidance literature:: (1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol; With water; sodium hydride; In tetrahydrofuran; at 23 ℃; for 0.166667h; Inert atmosphere;

carbon disulfide; In tetrahydrofuran; at 23 ℃; for 0.333333h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at 23 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol8018727

Reference yield: 71.0%

: 1070800-59-7
(1R,2S)-1-(3-benzyloxymethoxy-2-vinylphenyl)-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]but-3-en-1-ol

: 1070800-60-0
(1R,2S)-5-benzyloxymethoxy-2-[(1S,2S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxaspiro[4.4]non-2-yl)-2-(2,2,2-trichloroethoxymethoxy)ethyl]-1,2-dihydronaphthalen-1-ol

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; titanium(IV) isopropylate; In dichloromethane; at 40 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol8018727