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Dimethylsilylbis(cyclopentadienyl)zirconium dichloride

Base Information Edit
  • Chemical Name:Dimethylsilylbis(cyclopentadienyl)zirconium dichloride
  • CAS No.:86050-32-0
  • Molecular Formula:C12H14Cl2SiZr
  • Molecular Weight:348.459
  • Hs Code.:
  • Mol file:86050-32-0.mol
Dimethylsilylbis(cyclopentadienyl)zirconium dichloride

Synonyms:Silane,di-1,3-cyclopentadien-1-yldimethyl-, zirconium complex;Dichloro(dimethylsilylenebis(h5-cyclopentadienylidene))zirconium;Dichloro[dimethylsilylenebis(h5-cyclopentadienylidene)]zirconium;Dichloro[dimethylsilylenebis(cyclopentadienylidene)]zirconium;Dichloro[dimethylsilylenebis-h5-cyclopentadienyl]zirconium;Dimethylsilanediylbis(cyclopentadienyl)zirconiumdichloride;Dimethylsilyl bis(cyclopentadienyl)zirconium dichloride;Dimethylsilylenebis(cyclopentadienyl)zirconium dichloride;

Suppliers and Price of Dimethylsilylbis(cyclopentadienyl)zirconium dichloride
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Strem Chemicals
  • [Dimethylbis(cyclopentadienyl)silyl]zirconium dichloride, min. 98%
  • 1g
  • $ 174.00
  • Strem Chemicals
  • [Dimethylbis(cyclopentadienyl)silyl]zirconium dichloride, min. 98%
  • 5g
  • $ 692.00
  • Biosynth Carbosynth
  • (Dimethylbis(cyclopentadienyl)silyl)zirconiumdichloride
  • 250 mg
  • $ 600.00
  • Biosynth Carbosynth
  • (Dimethylbis(cyclopentadienyl)silyl)zirconiumdichloride
  • 100 mg
  • $ 320.00
  • Biosynth Carbosynth
  • (Dimethylbis(cyclopentadienyl)silyl)zirconiumdichloride
  • 50 mg
  • $ 250.00
  • Biosynth Carbosynth
  • (Dimethylbis(cyclopentadienyl)silyl)zirconiumdichloride
  • 25 mg
  • $ 200.00
  • Biosynth Carbosynth
  • (Dimethylbis(cyclopentadienyl)silyl)zirconiumdichloride
  • 500 mg
  • $ 850.00
  • American Custom Chemicals Corporation
  • (DIMETHYLBIS(CYCLOPENTADIENYL)SILYL)ZIRCONIUM DICHLORIDE 95.00%
  • 5G
  • $ 1428.62
  • American Custom Chemicals Corporation
  • (DIMETHYLBIS(CYCLOPENTADIENYL)SILYL)ZIRCONIUM DICHLORIDE 95.00%
  • 1G
  • $ 766.46
Total 18 raw suppliers
Chemical Property of Dimethylsilylbis(cyclopentadienyl)zirconium dichloride Edit
Chemical Property:
  • PSA:0.00000 
  • LogP:4.22980 
  • Sensitive.:moisture sensitive 
Purity/Quality:

98%Min *data from raw suppliers

[Dimethylbis(cyclopentadienyl)silyl]zirconium dichloride, min. 98% *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes: 
MSDS Files:

SDS file from LookChem

Useful:
Technology Process of Dimethylsilylbis(cyclopentadienyl)zirconium dichloride

There total 10 articles about Dimethylsilylbis(cyclopentadienyl)zirconium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With trimethyltin(IV)chloride; In diethyl ether; toluene; inert atmosphere; addn. of Me3SnCl to Li-salt in Et2O at -40°C, warming to room temp., evapn., addn. of ZrCl4 suspn. in toluene, stirring(80°C, 4 h); evapn. (80-90°C, 1 torr), recrystn. or washing;
Guidance literature:
In tetrahydrofuran; toluene; dry Ar-atmosphere; slow addn. of ligand (in THF) to equimolar amt. of Zr-compd. (in PhMe) at -10°C, stirring at room temp. for 14 h; solvent removal (vac.), washing (cold hexane), extn. into CH2Cl2 (Soxhlet), concn., cooling to 0°C (pptn.), recrystn. (PhMe/hexane);
DOI:10.1016/S0022-328X(99)00362-9
Guidance literature:
With n-butyllithium; In diethyl ether; hexane; byproducts: butane, LiCl; (Ar); addn. of a soln. of lithium compd. in hexane to a soln. of ligand in Et2O, stirring for 8 h at room temp., cooling to -78°C, addn. of ZrCl4, warming to room temp. within 6 h, stirring for 6 h; evapn., suspn. in CH2Cl2, filtration through Na2SO4, evapn., washing with pentane and Et2O, crystn. (CH2Cl2, -28°C);
DOI:10.1016/S0022-328X(02)01673-X
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