4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE

Base Information

• Chemical Name: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE
• CAS No.: 129077-51-6
• Molecular Formula: C21H14N4O2
• Molecular Weight: 354.368
• Mol file: 129077-51-6.mol

Synonyms:4'-(4-Nitrophenyl)-2,2':6',2''-terpyridine;

Chemical Property of 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE

Chemical Property:

• Melting Point: 158-159 °C(Solv: ethanol (64-17-5))
• Boiling Point: 536.1 °C at 760 mmHg
• PKA: 4.41±0.22(Predicted)
• Flash Point: 278 °C
• PSA: 84.49000
• Density: 1.28 g/cm³
• LogP: 5.30400
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99%, ^*data from raw suppliers

4''-(4-Nitrophenyl)-2,2'':6'',2''''-terpyridine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE

There total 11 articles about 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide (26482-00-8) + (2E)-3-(4-nitrophenyl)-1-(pyridin-2-yl)prop-2-en-1-one (18451-69-9) → 4’-(4-nitrophenyl)-2,2’,6’,2’’-terpyridine (129077-51-6)

Guidance literature:

With ammonium acetate; In methanol; for 24h; Heating;

DOI:10.1002/hlca.19930760323

Reference yield: 92.0%

2-acetylpyridine (1122-62-9) + 4-nitrobenzaldehdye (555-16-8) → 4’-(4-nitrophenyl)-2,2’,6’,2’’-terpyridine (129077-51-6)

Guidance literature:

With ammonium acetate; In water; at 130 ℃; for 0.366667h; microwave irradiation;

DOI:10.1016/j.tet.2006.10.069

Reference yield: 64.0%

p-nitrobenzene iodide (636-98-6) + 4'-((neopentyl glycolato)boron)-2,2':6',2''-terpyridine (381218-94-6) → 4’-(4-nitrophenyl)-2,2’,6’,2’’-terpyridine (129077-51-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In tetrahydrofuran; Heating;

DOI:10.1039/b205330f

upstream raw materials:

1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide

(2E)-3-(4-nitrophenyl)-1-(pyridin-2-yl)prop-2-en-1-one

p-nitrobenzene iodide

4'-{[(Trifluoromethyl)sulfonyl]oxy}-2,2':6',2''-terpyridine

Downstream raw materials:

4'-(4'''-Nitrophenyl)-2,2':6',2''-terpyridine N,N''-dioxide

4′-(4-amino-phenyl)-2,2′:6′,2′′-terpyridine

[IrCl₃(4'-(phenyl-p-nitro)-2,2':6',2''-terpyridine)]

[Ru(4'-(phenyl-p-nitro)-2,2':6',2''-terpyridine)(CF₃CO₂)3]

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