3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

Base Information

Chemical Name:3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone
CAS No.:220008-41-3
Molecular Formula:C₂₃H₃₆O₂S₂Si
Molecular Weight:436.755
Hs Code.:

Synonyms:3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

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Chemical Property of 3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

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Technology Process of 3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

There total 5 articles about 3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 930-68-7
cyclohexenone

: 220008-40-2
tert-Butyl-(2-[1,3]dithian-2-yl-benzyloxy)-dimethyl-silane

: 220008-41-3
3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at -78 - 0 ℃;
DOI:10.1039/a806808i

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 220008-41-3
3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / dimethylformamide / Ambient temperature

2: 73 percent / LDA / tetrahydrofuran / -78 - 0 °C

With 1H-imidazole; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1039/a806808i

Reference yield:

: 119-67-5
o-carboxybenzaldehyde

: 220008-41-3
3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone

Guidance literature:: Multi-step reaction with 4 steps

1: BF₃*OEt₂ / CH₂Cl₂ / Ambient temperature

2: LAH / tetrahydrofuran / Ambient temperature

3: imidazole / dimethylformamide / Ambient temperature

4: 73 percent / LDA / tetrahydrofuran / -78 - 0 °C

With 1H-imidazole; lithium aluminium tetrahydride; boron trifluoride diethyl etherate; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/a806808i