(3-Iodopropyl)trimethoxysilane

Base Information

• Chemical Name: (3-Iodopropyl)trimethoxysilane
• CAS No.: 14867-28-8
• Molecular Formula: C6H15IO3Si
• Molecular Weight: 290.173
• Hs Code.: 29319090
• European Community (EC) Number: 683-381-1
• DSSTox Substance ID: DTXSID10374769
• Nikkaji Number: J364.624F
• Wikidata: Q82163333
• Mol file: 14867-28-8.mol

Synonyms:(3-Iodopropyl)trimethoxysilane;14867-28-8;3-Iodopropyltrimethoxysilane;3-iodopropyl(trimethoxy)silane;3-iodopropyl trimethoxysilane;iodopropyltrimethoxysilane;iodopropyltrimethoxy silane;trimethoxysilylpropyl iodide;C6H15IO3Si;3-Iopdopropyl trimethoxysilane;SCHEMBL404785;3-iodanylpropyl(trimethoxy)silane;DTXSID10374769;NILZGRNPRBIQOG-UHFFFAOYSA-N;MFCD00054838;AKOS015914766;FS-5030;CS-0141323;I1106;I11240;(3-Iodopropyl)trimethoxysilane, >=95.0% (GC);A808799

Chemical Property of (3-Iodopropyl)trimethoxysilane

Chemical Property:

• Vapor Pressure: 0.515mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: n20/D 1.473(lit.)
• Boiling Point: 198.129 °C at 760 mmHg
• Flash Point: 73.626 °C
• PSA: 27.69000
• Density: 1.442 g/cm³
• LogP: 1.68960
• Storage Temp.: 2-8°C(protect from light)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 289.98352
• Heavy Atom Count: 11
• Complexity: 89.6

Purity/Quality:

99% ^*data from raw suppliers

(3-Iodopropyl)trimethoxysilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](CCCI)(OC)OC
• Uses: (3-iodopropyl)trimethoxysilane may be used to organically modify mesoporous silica support by grafting method.{85} The product may be used to synthesize heavy atom-concentrated?organically modified silica?nanoparticles.{86}

Technology Process of (3-Iodopropyl)trimethoxysilane

There total 2 articles about (3-Iodopropyl)trimethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

3-Chloropropyltrimethoxysilan (2530-87-2) → 3-iodopropyltrimethoxysilane (14867-28-8)

Guidance literature:

With sodium iodide; In acetone; Inert atmosphere; Reflux;

DOI:10.1002/chem.201400392

Reference yield:

→ 3-iodopropyltrimethoxysilane (14867-28-8)

Guidance literature:

Cl(CH2)3Si(OCH3)3, NaI, in Acn., Kochen, 2 h;

Reference yield: 98.0%

2,2'-(((azanediylbis(propane-3,1-diyl))bis(azanylylidene))bis(methanylylidene))diphenol + 3-iodopropyltrimethoxysilane (14867-28-8) → (CH3O)3SiC3H6N(C3H6NCHC6H4OH)2 (635299-18-2)

Guidance literature:

With potassium carbonate; In acetonitrile; for 22h; Heating;

DOI:10.1039/b304032a

upstream raw materials:

3-Chloropropyltrimethoxysilan

Downstream raw materials:

(CH₃O)3SiC₃H₆N(C₃H₆NCHC₆H₄OH)2

1-[3-(trimethoxysilyl)propyl]imidazole

Pd-Cl 3-((3,5-bis(phenylsulfanylmethyl)phenoxy)propyltrimethoxysilane

C₃₉H₅₄N₃O₃Si⁽¹⁺⁾*I^(1-)

Refernces

• 1、 Hajipour, Abdol R.,Azizi, Ghobad. "Palladium-quaternary phosphonium phase transfer catalyst brush assembly as reusable and environmentally benign catalyst for coupling of aryl halides and sodium tetraphenylborate in neat water". . p. 712 - 717. Retrieved 2015.
• 2、 Kronstein, Martin,Akbarzadeh, Johanna,Drechsel, Christina,Peterlik, Herwig,Neouze, Marie-Alexandra. "Tailoring photoluminescence properties in ionic nanoparticle networks". . p. 10763 - 10774. Retrieved 2014.
• 3、 Min, Jiakang,Lin, Yichao,Zheng, Jun,Tang, Tao. "A novel strategy to synthesize well-defined PS brushes on silica particles by combination of lithium-iodine exchange (LIE) and surface-initiated living anionic polymerization (SI-LAP)". . p. 5921 - 5924. Retrieved 2015.
• 4、 Hajipour, Abdol R.,Khorsandi, Zahra,Fatemeh Mohammadi Metkazini. "Palladium nanoparticles supported on cysteine-functionalized MNPs as robust recyclable catalysts for fast O- and N-arylation reactions in green media". . . Retrieved 2019/08/12.
• 5、 Tavakol, Hossein,Keshavarzipour, Fariba. "Preparation of choline chloride–urea deep eutectic solvent-modified magnetic nanoparticles for synthesis of various 2-amino-4H-pyran derivatives in water solution". . p. 2372 - 2380. Retrieved 2017/09/30.