(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Base Information

Chemical Name:(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester
CAS No.:185380-88-5
Molecular Formula:C₇₉H₈₀O₁₅
Molecular Weight:1269.5
Hs Code.:

(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Synonyms:(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Suppliers and Price of (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

There total 23 articles about (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 4539-78-0
2,3,4-tri-O-benzyl-D-glucopyranosideuronic acid benzyl ester

: 185380-65-8
benzyl O-(2,5-di-O-benzyl-α-L-arabinofuranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside

: benzyl O-(2,5-di-O-benzyl-3-O-p-nitrobenzenesulfonyl-α-L-arabinofuranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside

: (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

: 185380-88-5
(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Guidance literature:: With silver trifluoromethanesulfonate; triethylamine; 4-Nitrobenzenesulfonyl chloride; In dichloromethane; at 0 ℃;
DOI:10.1246/bcsj.69.3247

Reference yield: 41.0%

: 4539-78-0
2,3,4-tri-O-benzyl-D-glucopyranosideuronic acid benzyl ester

: 98-74-8
4-Nitrobenzenesulfonyl chloride

: 185380-65-8
benzyl O-(2,5-di-O-benzyl-α-L-arabinofuranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside

: benzyl O-(2,5-di-O-benzyl-3-O-p-nitrobenzenesulfonyl-α-L-arabinofuranosyl)-(1-3)-2,4-di-O-benzyl-α-D-xylopyranoside

: (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

: 185380-88-5
(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Guidance literature:: With silver trifluoromethanesulfonate; triethylamine; In dichloromethane; at 0 ℃;
DOI:10.1246/bcsj.69.3247

Reference yield:

: 100-44-7
benzyl chloride

: 185380-88-5
(2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5S)-4-benzyloxy-2-benzyloxymethyl-5-((2S,3R,4S,5R)-2,3,5-tris-benzyloxy-tetrahydro-pyran-4-yloxy)-tetrahydro-furan-3-yloxy]-tetrahydro-pyran-2-carboxylic acid benzyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 68 percent / KOH / 1.5 h / 120 °C

2: 79 percent / aq. H₂SO₄, AcOH / 1.5 h / 75 °C

3: 52 percent / trimethylsilyl bromide, CoBr₂, tetrabutylammonium bromide, molecular sieves 3A / CH₂Cl₂ / Ambient temperature

4: 70 percent / NaOAc, aq. AcOH, PdCl₂ / 0.5 h / 60 °C

5: 41 percent / p-NO₂C₆H₄SO₂Cl, CF₃SO₃Ag, Et₃N / CH₂Cl₂ / 0 °C

With potassium hydroxide; trimethylsilyl bromide; 3 A molecular sieve; sulfuric acid; tetrabutylammomium bromide; sodium acetate; silver trifluoromethanesulfonate; acetic acid; triethylamine; 4-Nitrobenzenesulfonyl chloride; cobalt(II) bromide; palladium dichloride; In dichloromethane;
DOI:10.1246/bcsj.69.3247