4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline

Base Information

• Chemical Name: 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline
• CAS No.: 180133-86-2
• Molecular Formula: C₄₈H₄₈N₂O₂
• Molecular Weight: 684.921
• Mol file: 180133-86-2.mol

Synonyms:4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline

Chemical Property of 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline

There total 1 articles about 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,7-Dihexyl-2,9-bis-(4'-triisopropylsilanyloxy-biphenyl-4-yl)-[1,10]phenanthroline → 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline (180133-86-2)

Guidance literature:

With tetrabutyl ammonium fluoride;

DOI:10.1039/CC9960001243

Reference yield: 55.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + 3,5-Bis-{2-[2-(2-iodo-ethoxy)-ethoxy]-ethoxy}-benzoic acid methyl ester (180133-84-0) + 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline (180133-86-2) → [Cu(C68H76N2O10)2](1+) (180133-88-4)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; 60°C;

DOI:10.1039/CC9960001243

Reference yield: 10.0%

4-(4-bromophenyl)pyridine (39795-60-3) + 4,7-D-(n-Hexyl)-2,9-di-[4'-(p-hydroxyphenyl)phenyl]-1,10-phenanthroline (180133-86-2) → 4,7-di-n-hexyl-2,9-bis[4'-(4-pyridyl-4-phenoxy)biphenyl]-1,10-phenanthroline (360564-69-8)

Guidance literature:

With tetrakis(actonitrile)copper(I) hexafluorophosphate; Cs₂O₃; 4 A molecular sieve; In N,N-dimethyl-formamide; toluene; at 110 ℃; for 72h;

DOI:10.1021/ja021370l

Downstream raw materials:

4,7-di-n-hexyl-2,9-bis[4'-(4-pyridyl-4-phenoxy)biphenyl]-1,10-phenanthroline

[Cu(C₆₈H₇₆N₂O₁₀)2]⁽¹⁺⁾