Technology Process of 4-[bis(2-bromo-9,9-dihexyl-7-fluorenyl)amino]benzaldehyde
There total 5 articles about 4-[bis(2-bromo-9,9-dihexyl-7-fluorenyl)amino]benzaldehyde which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
trichlorophosphate;
In
1,2-dichloro-ethane;
at 0 - 90 ℃;
for 12h;
DOI:10.1002/pola.24604
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1,10-Phenanthroline; copper(l) chloride; potassium hydroxide / toluene / 12 h / 125 °C / Inert atmosphere
2: trichlorophosphate / 1,2-dichloro-ethane / 12 h / 0 - 90 °C
With
1,10-Phenanthroline; copper(l) chloride; potassium hydroxide; trichlorophosphate;
In
1,2-dichloro-ethane; toluene;
1: Ullmann coupling / 2: Vilsmeier formylation;
DOI:10.1002/pola.24604
- Guidance literature:
-
Multi-step reaction with 4 steps
1: tetrabutylammomium bromide; sodium hydroxide / tetrahydrofuran; water / 12 h / 80 °C / Inert atmosphere
2: sulfuric acid; iodine; periodic acid / water; acetic acid / 12 h / 80 °C
3: 1,10-Phenanthroline; copper(l) chloride; potassium hydroxide / toluene / 12 h / 125 °C / Inert atmosphere
4: trichlorophosphate / 1,2-dichloro-ethane / 12 h / 0 - 90 °C
With
1,10-Phenanthroline; sulfuric acid; tetrabutylammomium bromide; iodine; periodic acid; copper(l) chloride; potassium hydroxide; sodium hydroxide; trichlorophosphate;
In
tetrahydrofuran; water; acetic acid; 1,2-dichloro-ethane; toluene;
3: Ullmann coupling / 4: Vilsmeier formylation;
DOI:10.1002/pola.24604
