C₁₅H₂₀OSi

Base Information

• Chemical Name: C₁₅H₂₀OSi
• CAS No.: 1272341-23-7
• Molecular Formula: C₁₅H₂₀OSi
• Molecular Weight: 244.409
• Mol file: 1272341-23-7.mol

Synonyms:C₁₅H₂₀OSi

Chemical Property of C₁₅H₂₀OSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₅H₂₀OSi

There total 5 articles about C₁₅H₂₀OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

6-methylcyclohex-2-en-1-one (6610-21-5) + 1,2-diphenyltetramethyldisilane (1145-98-8) → C15H20OSi (1272341-23-7)

Guidance literature:

1,2-diphenyltetramethyldisilane; With N,N,N,N,N,N-hexamethylphosphoric triamide; methyllithium; In tetrahydrofuran; diethyl ether; at -78 - 0 ℃; for 0.0833333h; Inert atmosphere;

6-methylcyclohex-2-en-1-one; In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere;

With bis(η3-allyl-μ-chloropalladium(II)); allyl diethyl phosphate; In tetrahydrofuran; diethyl ether; at -78 - 60 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/anie.201810566

Reference yield: 52.0%

C15H22OSi (1272341-10-2) → C15H20OSi (1272341-23-7)

Guidance literature:

With silica gel; pyridinium chlorochromate; In 1,2-dichloro-ethane; at 85 ℃; for 0.0833333h;

DOI:10.1016/j.cclet.2010.10.018

Reference yield:

dimethyl(phenyl)silyl lithium (3839-31-4) + 6-methylcyclohex-2-en-1-one (6610-21-5) → C15H20OSi (1272341-23-7)

Guidance literature:

dimethyl(phenyl)silyl lithium; 6-methylcyclohex-2-en-1-one; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.5h; Inert atmosphere; Sealed tube;

With bis(η3-allyl-μ-chloropalladium(II)); allyl diethyl phosphate; In tetrahydrofuran; diethyl ether; at 0 - 23 ℃; for 0.5h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.7b13189

upstream raw materials:

C₁₅H₂₂OSi

1,2-diphenyltetramethyldisilane

2-methyl-5-(prop-1-en-2-yl)cyclohexanone

dimethyl(phenyl)silyl lithium