cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Base Information

Chemical Name:cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]
CAS No.:698386-69-5
Molecular Formula:C₄₈H₃₈P₂PtS₂
Molecular Weight:935.989
Hs Code.:

cis-[platinum(II)(PPh<sub>3</sub>)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Synonyms:cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Suppliers and Price of cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

There total 2 articles about cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 117056-97-0
5,6-dihydroacenaphtho<5.6-cd>-1,2-dithiolate

: 698386-69-5
cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Guidance literature:: With lithium triethylborohydride; In tetrahydrofuran; at 20 ℃; for 48h; Inert atmosphere; Schlenk technique; Gas phase;
DOI:10.1002/ejic.201200967

Reference yield:

: 19190-91-1
5,6-dibromoacenaphthene

: 698386-69-5
cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)]

Guidance literature:: Multi-step reaction with 2 steps

1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / hexane; diethyl ether / 4.5 h / -78 - -40 °C / Inert atmosphere; Schlenk technique; Glovebox

2: lithium triethylborohydride / tetrahydrofuran / 48 h / 20 °C / Inert atmosphere; Schlenk technique; Gas phase

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; lithium triethylborohydride; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/ejic.201200967