5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin

Base Information

• Chemical Name: 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin
• CAS No.: 22843-73-8
• Molecular Formula: C44H26 N8 O8
• Molecular Weight: 794.739
• Hs Code.: 2933990090
• Mol file: 22843-73-8.mol

Synonyms:Porphine,5,10,15,20-tetrakis(p-nitrophenyl)- (8CI);5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin; Tetra(p-nitrophenyl)porphyrin;meso-Tetra(4-nitrophenyl)porphyrin; meso-Tetrakis(4-nitrophenyl)porphine;meso-Tetrakis(4-nitrophenyl)porphyrin

Chemical Property of 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin

Chemical Property:

• Melting Point: >27 °C
• PSA: 239.58000
• Density: 1.478g/cm³
• LogP: 8.59180
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99%, ^*data from raw suppliers

5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin

There total 14 articles about 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8)

Guidance literature:

With nitric acid; In chloroform; at 0 ℃; for 0.833333h; Inert atmosphere;

DOI:10.1016/j.tet.2011.06.031

Reference yield: 57.0%

pyrrole (109-97-7,30604-81-0) + 4-nitrobenzaldehdye (555-16-8) → 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8)

Guidance literature:

With propionic acid; In N,N-dimethyl-formamide; at 70 - 140 ℃; Temperature;

Reference yield: 28.0%

4-nitrobenzaldehdye (555-16-8) + 5-phenyldipyrromethane (107798-98-1) → 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8)

Guidance literature:

4-nitrobenzaldehdye; 5-phenyldipyrromethane; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Darkness;

With chloranil; In dichloromethane; for 1.5h; Inert atmosphere; Reflux;

DOI:10.1002/chir.23043

upstream raw materials:

pyrrole

4-nitrobenzaldehdye

5,15,10,20-tetraphenylporphyrin

para-acetamidobenzaldehyde

Downstream raw materials:

5,10,15,20-tetra(4-nitrophenyl) porphyrinato iron chloride

5,10,15,20-tetra(4-nitrophenyl) porphyrinato manganese chloride

5,10,15,20-tetra(4-nitrophenyl) porphyrinato cobalt chloride

5,10,15,20-tetrakis(para-aminophenyl)porphyrin nickel(II)

Refernces

• 1、 Yang, Zhaohui,Yang, Linglu,Zhang, Maofeng,Cao, Weixiao. "Stable ultrathin films and hollow spheres fabricated from P(DSS-VP) and porphyrin derivatives". . p. 4723 - 4727. Retrieved 2005.
• 2、 Xu, Yanfei,Li, Zhi,Zhang, Fan,Zhuang, Xiaodong,Zeng, Zheng,Wei, Jianjun. "New nitrogen-rich azo-bridged porphyrin-conjugated microporous networks for high performance of gas capture and storage". . p. 30048 - 30055. Retrieved 2016.
• 3、 -. "Synthesis method of tetra (4-aminophenyl) porphyrin metal complex". Paragraph 0081-0083. . Retrieved 2021/06/13.
• 4、 Guo, Ding,Li, Cheng,Liu, Genyan,Luo, Xiaogang,Wu, Fengshou,Zhang, Juan. "Metalloporphyrin-based porous organic polymer as an efficient catalyst for cycloaddition of epoxides and CO2". . . Retrieved 2020/10/13.