11-CHLORO-1-UNDECENE

Base Information

• Chemical Name: 11-CHLORO-1-UNDECENE
• CAS No.: 872-17-3
• Molecular Formula: C11H21Cl
• Molecular Weight: 188.741
• Hs Code.: 29032900
• Mol file: 872-17-3.mol

Synonyms:1-Chloro-10-undecene;10-Undecenyl chloride;11-Chloro-1-undecene;w-Chloroundecene;

Chemical Property of 11-CHLORO-1-UNDECENE

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 0.0739mmHg at 25°C
• Refractive Index: n20/D 1.4510(lit.)
• Boiling Point: 236.1 °C at 760 mmHg
• Flash Point: 95.2 °C
• PSA: 0.00000
• Density: 0.871 g/cm³
• LogP: 4.53200
• Water Solubility.: Soluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

11-Chloro-1-undecene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,Xi
• Hazard Codes: Xn,Xi
• Statements: 36/37/38-22
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 11-Chloro-1-undecene is used in copolymerizations of propylene , preparation of unsaturated fatty acids, terpolymerizations with ethylene and propylene catalyzed by 2/mao.

Technology Process of 11-CHLORO-1-UNDECENE

There total 1 articles about 11-CHLORO-1-UNDECENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

(((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane) (1584705-82-7) + undec-10-en-1-ylboronic acid → 1-undecene (821-95-4) + 11-chloroundec-1-ene (872-17-3) + 1-iodo-10-undecene (7766-49-6) + (trifluoromethyl)(undec-10-en-1-yl)sulfane

Guidance literature:

With [2,2]bipyridinyl; copper(II) choride dihydrate; potassium carbonate; In 1,2-dichloro-ethane; at 120 ℃; for 12h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/ol502132j

Reference yield: 97.0%

11-chloroundec-1-ene (872-17-3) → 1-chloroundecane (2473-03-2)

Guidance literature:

With ethanol; (^BQ?NC^OP)IrHCl; sodium t-butanolate; at 60 ℃; for 2h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/jacs.8b01038

Reference yield: 93.0%

11-chloroundec-1-ene (872-17-3) + cyclohex-1-en-1-yl trifluoromethane sulfonate (28075-50-5) + phenylboronic acid (98-80-6) → C23H35Cl (1286254-47-4)

Guidance literature:

With potassium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In N,N-dimethyl acetamide; at 55 ℃; for 12h; regioselective reaction;

DOI:10.1021/ja201358b

upstream raw materials:

(((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane)

Downstream raw materials:

11-chloroundecyltrichlorosilane

(undec-10-en-1-yloxy)benzene

1-Chlorohexadecan

undec-10-enamide

Refernces