N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine

Base Information

• Chemical Name: N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine
• CAS No.: 1415041-30-3
• Molecular Formula: C₃₇H₅₆N₂P₂
• Molecular Weight: 590.813
• Mol file: 1415041-30-3.mol

Synonyms:N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine

Chemical Property of N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine

There total 1 articles about N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + naphthalene-1,8-diamine (479-27-6) + dicyclohexylphosphane (829-84-5) → N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine (1415041-30-3)

Guidance literature:

Inert atmosphere; Schlenk technique;

DOI:10.1039/c8gc03094d

Reference yield: 93.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine (1415041-30-3) → [IrHCl(CO){κ3-P,C,P′-CH(NCH2PCy2)2C10H6}] (1415041-33-6)

Guidance literature:

at 20 ℃; for 2h;

DOI:10.1021/om300897w

Reference yield: 93.0%

Wilkinson's catalyst (14694-95-2) + N,N′-bis(dicyclohexylphoshinomethyl)-2,3-dihydroperimidine (1415041-30-3) → [RhCl{κ3-P,C,P′=C(NCH2PCy2)2C10H6}]

Guidance literature:

In tetrahydrofuran; for 1.5h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c8gc03094d

upstream raw materials:

formaldehyd

naphthalene-1,8-diamine

dicyclohexylphosphane

Downstream raw materials:

[IrHCl(CO){κ³-P,C,P′-CH(NCH₂PCy₂)₂C₁₀H₆}]

[RuCl(Ph)(CO){κ³-P,N,P'-CH₂(NCH₂PCy₂)₂C₁₀H₆}]