(-)-menthyl 2-phenylpropanoate

Base Information

• Chemical Name: (-)-menthyl 2-phenylpropanoate
• CAS No.: 32213-55-1
• Molecular Formula: C₁₉H₂₈O₂
• Molecular Weight: 288.43
• Mol file: 32213-55-1.mol

Synonyms:(-)-menthyl 2-phenylpropanoate

Chemical Property of (-)-menthyl 2-phenylpropanoate

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-PHENYL-PROPIONIC ACID 2-ISOPROPYL-5-METHYL-CYCLOHEXYL ESTER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-menthyl 2-phenylpropanoate

There total 4 articles about (-)-menthyl 2-phenylpropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.8%

2-Phenylpropanal (34713-70-7) → (-)-menthyl 2-phenylpropanoate (32213-55-1) + (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (81115-66-4)

Guidance literature:

With aluminium menthyloxide; In dichloromethane; at -78 ℃; for 4h;

DOI:10.1039/P19810003034

Reference yield:

(-)-menthol (2216-51-5) + 2-Phenylpropanal (34713-70-7) → (2R,5S)-menthone (10458-14-7,14073-97-3,17627-49-5,7786-64-3) + (-)-menthyl 2-phenylpropanoate (32213-55-1) + (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (81115-66-4)

Guidance literature:

With aluminium; Yield given. Multistep reaction. Yields of byproduct given; 1) benzene, heating, 128 h; 2) CH₂Cl₂, -78 deg C, 4 h;

DOI:10.1039/P19810003034

Reference yield:

(-)-menthol (2216-51-5) + 2-Phenylpropanal (34713-70-7) → (2R,5S)-menthone (10458-14-7,14073-97-3,17627-49-5,7786-64-3) + (-)-menthyl 2-phenylpropanoate (32213-55-1) + (R)-2-phenylpropanal (93-53-8) + (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (81115-66-4)

Guidance literature:

With aluminium; Product distribution; Mechanism; multistep reaction: 1) benzene, heating, 128 h; 2) CH₂Cl₂, -78 deg C; further alcohols; asymmetric induction;;

DOI:10.1039/P19810003034

upstream raw materials:

(-)-menthol

2-Phenylpropanal

(2S)-2-methyl-1-butanol