tetradecachloro-4-methoxytriphenylmethyl radical

Base Information

• Chemical Name: tetradecachloro-4-methoxytriphenylmethyl radical
• CAS No.: 71947-01-8
• Molecular Formula: C₂₀H₃Cl₁₄O
• Molecular Weight: 755.585
• Mol file: 71947-01-8.mol

Synonyms:tetradecachloro-4-methoxytriphenylmethyl radical

Chemical Property of tetradecachloro-4-methoxytriphenylmethyl radical

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetradecachloro-4-methoxytriphenylmethyl radical

There total 11 articles about tetradecachloro-4-methoxytriphenylmethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.3%

Tetra-n-butylammonium 4-methoxytetradecachlorotriphenylmethide (126061-92-5) → tetradecachloro-4-methoxytriphenylmethyl radical (71947-01-8)

Guidance literature:

With iodine; In tetrahydrofuran; for 2h;

DOI:10.1021/jo00297a017

Reference yield: 65.5%

4-H-tetradecachlorotriphenylmethyl radical (79855-13-3) + Tetra-n-butylammonium 4-methoxytetradecachlorotriphenylmethide (126061-92-5) → tetradecachloro-4-methoxytriphenylmethyl radical (71947-01-8) + Tetra-n-butylammonium 4H-tetradecachlorotriphenylmethide (126062-07-5)

Guidance literature:

In tetrahydrofuran; for 2h; Equilibrium constant; Thermodynamic data; Ambient temperature; ΔG(ET);

DOI:10.1021/jo00297a017

Reference yield: 0.25%

diazomethane (186581-53-3,908094-01-9,334-88-3) + bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical (67173-39-1) → perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone (29972-98-3) + tetradecachloro-4-methoxytriphenylmethyl radical (71947-01-8)

Guidance literature:

In diethyl ether;

DOI:10.1021/jo00002a063

upstream raw materials:

diazomethane

bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical

perchlorotriphenylmethyl radical

Tetra-n-butylammonium 4-methoxytetradecachlorotriphenylmethide

Downstream raw materials:

4-H-tetradecachlorotriphenylmethyl radical

Tetra-n-butylammonium 4-methoxytetradecachlorotriphenylmethide

tetradecachloro-4-methyltriphenylmethyl radical

perchlorotriphenylmethyl radical