29972-98-3Relevant academic research and scientific papers
"Spin-Charge Exchange" in Allodial Radical Ions, a Novel Intramolecular Single Electron Transfer Equilibrium
Ballester, Manuel,Pascual, Isabel,Riera, Juan,Castaner, Juan
, p. 217 - 225 (2007/10/02)
The intramolecular single-electron transfer in radical anions and radical cations, constituted by two identical triphenylmethyl moieties, has been studied.The preparation of the radical ions has been effected by mixing the corresponding stable diions (tet
Inert Carbon Free Radicals. 10. Chlorination of Perchlorotriphenylmethyl (PTM) Radical. Synthesis, Structure, and Reactivity of Perchloro(diphenylmethylene)cyclohexa-1,4-diene
Ballester, M.,Riera, J.,Castaner, J.,Carreras, C.,Ubierna, J. J.,et al.
, p. 4611 - 4615 (2007/10/02)
Perchlorotriphenylmethyl radical (PTM-radical) is the paradigm of the chlorine-shielded "inert free radicals" (IFRs), which owe their unique chemical inertia to the colossal overcrowding about their trivalent carbon.However, they are active in single elec
Inert Carbon Free Radicals. 4. Spin Labeling of Amino Acids and Peptides
Ballester, M.,Riera, J.,Castaner, J.,Rovira, C.,Veciana, J.,Onrubia, C.
, p. 3716 - 3720 (2007/10/02)
The first examples of spin labeling with inert free-radical reagents are presented.Those here described involve tagging of amino acids and peptides, the labeling reagents being tetradecachloro-4-(chlorocarbonyl)triphenylmethyl(2), 4-aminotetradecachlorotr
Inert Carbon Free Radicals. 2. Monofunctionalized Tetradecachlorotriphenylmethyl Radicals and Related Compounds
Ballester, M.,Castaner, J.,Riera, J.,Ibanez, A.,Pujadas, J.
, p. 259 - 264 (2007/10/02)
Perchlorinated triphenylmethyl radicals, and their nonradical α-H precursors, with hydrogen (2), carboxy (3), carbomethoxy (4), ammonium carboxylate (5), bromo (6), iodo (7), and methyl (8) substituents in the 4-position have been synthesized and their re
Inert Carbon Free Radicals. 3. Monofunctionalized Radicals from Perchlorotriphenylcarbenium Hexachloroantimonate
Ballester, Manuel,Riera, Juan,Castaner, Juan,Rodriguez, Antonio,Rovira, Concepcion,Veciana, Jaime
, p. 4498 - 4505 (2007/10/02)
Perchlorotriphenylcarbenium hexachloroantimonate (2) is prepared from perchlorotriphenylmethyl radical (PTM; 1) and SbCl5.Salt 2 by hydrolisis or ammonolysis yields perchlorofuchsone (3) or NH-tetradecachlorofuchsonimine (4), respectively, two quinonoid c
