CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

Base Information

• Chemical Name: CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
• CAS No.: 16592-65-7
• Molecular Formula: C54H45 Cl O9 P3 Rh
• Molecular Weight: 1069.23
• Mol file: 16592-65-7.mol

Synonyms:Rhodium,chlorotris(phosphorous acid)-, nonaphenyl ester (8CI); Rhodium,chlorotris(triphenyl phosphite-P)-; Chlorotris(triphenyl phosphite)rhodium

Chemical Property of CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

Chemical Property:

• Melting Point: 245-250 °C (dec.)
• PSA: 40.77000
• LogP: 11.02390
• Storage Temp.: 2-8°C
• Water Solubility.: insoluble

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xi:Irritant
• Statements: R36/38:
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

There total 6 articles about CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

triphenyl phosphite (101-02-0) + [(CH3)2NH2](1+)*[RhCl2(CO)2](1-)=[(CH3)2NH2](RhCl2(CO)2) (99943-85-8) → RhCl(P(OPh)3)3 (16592-65-7)

Guidance literature:

In N,N-dimethyl-formamide; reagents mixed at room temp.; cold water added, filtered, washed with water, elem. anal.;

DOI:10.1002/1099-0682(200109)2001:9<2327::AID-EJIC2327>3.0.CO;2-D

Reference yield:

triphenyl phosphite (101-02-0) + 2Rh(1+)*4P(OC6H5)3*2Cl(1-)={Rh(P(OC6H5)3)2Cl}2 → RhCl(P(OPh)3)3 (16592-65-7)

Guidance literature:

In dichloromethane; crystn. from chloroform/ethanol;

DOI:10.1016/0020-1650(69)80089-9

Reference yield:

triphenyl phosphite (101-02-0) + di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) → RhCl(P(OPh)3)3 (16592-65-7)

Guidance literature:

In benzene; Rh-complex and phosphite were mixed in benzene; not isolated;

DOI:10.1016/j.jorganchem.2003.09.054

upstream raw materials:

triphenyl phosphite

[(CH₃)2NH₂]⁽¹⁺⁾*[RhCl₂(CO)2]^(1-)=[(CH₃)2NH₂](RhCl₂(CO)2)

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

hydrogenchloride

Downstream raw materials:

Rh(P(OC₆H₅)3)4⁽¹⁺⁾*ClO₄^(1-) = Rh(P(OC₆H₅)3)4ClO₄

Rh(P(OC₆H₅)3)3(SCN)

Refernces

• 1、 Haines, L. M.. "". . p. 399 - 403. Retrieved 1969.
• 2、 Babij, Claudia,Farrar, David H.,Koshevoy, Igor O.,Poe, Anthony J.,Tunik, Sergey P.. "Kinetic studies of some substituted hexarhodium carbonyl clusters". . p. 116 - 122. Retrieved 2007/10/03.
• 3、 Serp, Philippe,Hernandez, Marc,Richard, Brigitte,Kalck, Philippe. "A facile route to carbonylhalogenometal complexes (M = Rh, Ir, Ru, Pt) by dimethylformamide decarbonylation". . p. 2327 - 2336. Retrieved 2007/10/03.