(E)-3-(4-chlorophenyl)allyl pivalate

Base Information

• Chemical Name: (E)-3-(4-chlorophenyl)allyl pivalate
• CAS No.: 1014394-73-0
• Molecular Formula: C₁₄H₁₇ClO₂
• Molecular Weight: 252.741
• Mol file: 1014394-73-0.mol

Synonyms:(E)-3-(4-chlorophenyl)allyl pivalate

Chemical Property of (E)-3-(4-chlorophenyl)allyl pivalate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (E)-3-(4-chlorophenyl)allyl pivalate

There total 2 articles about (E)-3-(4-chlorophenyl)allyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(E)-3-(p-chlorophenyl)prop-2-en-1-ol (24583-70-8) + pivaloyl chloride (3282-30-2) → (E)-3-(4-chlorophenyl)allyl pivalate (1014394-73-0)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 - 200 ℃; for 1.5h; Schlenk technique; Inert atmosphere;

DOI:10.1055/s-0036-1590914

Reference yield: 64.0%

(E)-3-(p-chlorophenyl)prop-2-en-1-ol (24583-70-8) + 2,2-dimethylpropanoic anhydride (1538-75-6) → (E)-3-(4-chlorophenyl)allyl pivalate (1014394-73-0)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jacs.6b10220

Reference yield: 76.0%

(E)-3-(4-chlorophenyl)allyl pivalate (1014394-73-0) + Pentafluorobenzene (363-72-4) → (E)-2,3,4,5,6-pentafluoro-4'-(3-(perfluorophenyl)prop-1-en-1-yl)-1,1'-biphenyl

Guidance literature:

With dichloro(1,5-cyclooctadiene)palladium(II); (2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine; caesium carbonate; In toluene; at 120 ℃; for 8h; Schlenk technique; Inert atmosphere;

DOI:10.1055/s-0036-1590914

upstream raw materials:

(E)-3-(p-chlorophenyl)prop-2-en-1-ol

2,2-dimethylpropanoic anhydride

pivaloyl chloride

Downstream raw materials:

1-chloro-4-(non-1-en-3-yl)benzene