(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Base Information

Chemical Name:(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene
CAS No.:114916-25-5
Molecular Formula:C₁₆H₁₉NO₄S₂
Molecular Weight:353.463
Hs Code.:

Synonyms:(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

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Chemical Property of (+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Chemical Property:

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Technology Process of (+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

There total 7 articles about (+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 114916-24-4
(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-benzyl alcohol

: 114916-25-5
(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 20h;
DOI:10.1016/S0040-4020(01)86895-2

Reference yield:

: 72856-73-6
2-methoxy-4-(methylsulfanyl)benzoic acid

: 114916-25-5
(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: Multi-step reaction with 7 steps

1: thionyl chloride / 2 h / Heating

2: 93 percent / triethylamine / toluene / Heating

3: 89 percent / tetrahydrofuran / 1 h / Heating

4: 23 percent / potassium permanganate / pyridine / 6 h / 50 - 60 °C

5: 50 percent / sodium hydroxide / methanol / 1 h / Heating

6: 52 percent / lithium aluminium hydride / tetrahydrofuran

7: 72 percent / H₂ / 5 percent palladised charcoal / methanol / 20 h

With sodium hydroxide; potassium permanganate; lithium aluminium tetrahydride; thionyl chloride; hydrogen; triethylamine; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; toluene;
DOI:10.1016/S0040-4020(01)86895-2

Reference yield:

: 69883-78-9
2-methoxy-4-(methylthio)benzoyl chloride

: 114916-25-5
(+)-2-methoxy-4-(S-methyl-N-<(4-methylphenyl)-sulfonyl>-sulfonimidoyl)-toluene

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / triethylamine / toluene / Heating

2: 89 percent / tetrahydrofuran / 1 h / Heating

3: 23 percent / potassium permanganate / pyridine / 6 h / 50 - 60 °C

4: 50 percent / sodium hydroxide / methanol / 1 h / Heating

5: 52 percent / lithium aluminium hydride / tetrahydrofuran

6: 72 percent / H₂ / 5 percent palladised charcoal / methanol / 20 h

With sodium hydroxide; potassium permanganate; lithium aluminium tetrahydride; hydrogen; triethylamine; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; toluene;
DOI:10.1016/S0040-4020(01)86895-2