Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂

Base Information

• Chemical Name: Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂
• CAS No.: 150771-13-4
• Molecular Formula: CH₂Cl₂*C₂₉H₄₂P₂RhS*ClO₄
• Molecular Weight: 771.955
• Mol file: 150771-13-4.mol

Synonyms:Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂

Chemical Property of Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂

There total 1 articles about Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + sodium perchlorate monohydrate (7791-07-3) + (Di-tert-butyl-phosphinothioylmethyl)-diphenyl-phosphane (116460-75-4) → Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))(1+)*ClO4(1-)*CH2Cl2={Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))}(ClO4)*CH2Cl2 (150771-13-4)

Guidance literature:

In acetone; byproducts: NaCl; (at room temp., under N2); dropwise addn. of the ligand in acetone to a stirred soln. of the starting complex and NaClO4*H2O in acetone; after 2 h filtn. from NaCl, removal of the solvent under vac., residue is washed (diethyl ether), recrystn. (CH2Cl2/diethyl ether), elem. anal.;

DOI:10.1016/0022-328X(93)83192-X

Reference yield: 82.0%

Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))(1+)*ClO4(1-)*CH2Cl2={Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))}(ClO4)*CH2Cl2 (150771-13-4) → Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))={Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))} (150771-09-8)

Guidance literature:

With NaH; In tetrahydrofuran; (at room temp. under N2); NaH is added to a stirred soln. of the Rh complex; after 2 h filtn., removal of the solvent in vac., recrystn. of the residue (hexane), elem. anal.;

DOI:10.1016/0022-328X(93)83192-X

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

sodium perchlorate monohydrate

(Di-tert-butyl-phosphinothioylmethyl)-diphenyl-phosphane

Downstream raw materials:

Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}