1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

Base Information

Chemical Name:1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene
CAS No.:351153-90-7
Molecular Formula:C₁₆H₁₇ClO₅
Molecular Weight:324.761
Hs Code.:

Synonyms:1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

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Technology Process of 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

There total 7 articles about 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 106-39-8
bromochlorobenzene

: 2873-29-2
D-glucal triacetate

: 351153-90-7
1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

Guidance literature:: bromochlorobenzene; With n-butyllithium; zinc(II) chloride; In diethyl ether; at 0 - 20 ℃;

D-glucal triacetate; With boron trifluoride diethyl etherate; In diethyl ether; at -78 - 20 ℃;
DOI:10.1016/j.carres.2004.11.012

Reference yield: 74.0%

: 14752-66-0
sodium p-chlorobenzenesulphinate

: 2873-29-2
D-glucal triacetate

: 351153-90-7
1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

Guidance literature:: With lithium chloride; copper dichloride; palladium dichloride; In acetonitrile; at 75 ℃; for 8h; regioselective reaction; Schlenk technique; Sealed tube;
DOI:10.1002/ejoc.201403550

Reference yield: 71.0%

: di(4-chlorophenyl)iodonium trifluoromethanesulfonate

: 2873-29-2
D-glucal triacetate

: 351153-90-7
1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; tetrabutyl-ammonium chloride; triethylamine; In N,N-dimethyl-formamide; at 125 ℃; for 48h; stereoselective reaction; Sealed tube;
DOI:10.1039/d0ob00247j