1-phenylvinyl cyclohexa-1,3-dienecarboxylate

Base Information

• Chemical Name: 1-phenylvinyl cyclohexa-1,3-dienecarboxylate
• CAS No.: 1627214-58-7
• Molecular Formula: C₁₅H₁₄O₂
• Molecular Weight: 226.275
• Mol file: 1627214-58-7.mol

Synonyms:1-phenylvinyl cyclohexa-1,3-dienecarboxylate

Chemical Property of 1-phenylvinyl cyclohexa-1,3-dienecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1-phenylvinyl cyclohexa-1,3-dienecarboxylate

There total 2 articles about 1-phenylvinyl cyclohexa-1,3-dienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

1-styrenyloxytrimethylsilane (13735-81-4) + C7H7FO → 1-phenylvinyl cyclohexa-1,3-dienecarboxylate (1627214-58-7)

Guidance literature:

With dmap; In acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.201402067

Reference yield:

cyclohexa-1,3-diene-1-carboxylic acid (2206-65-7) → 1-phenylvinyl cyclohexa-1,3-dienecarboxylate (1627214-58-7)

Guidance literature:

Multi-step reaction with 2 steps

1: diethylamino-sulfur trifluoride / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

2: dmap / acetonitrile / 1 h / 20 °C / Inert atmosphere

With dmap; diethylamino-sulfur trifluoride; In dichloromethane; acetonitrile;

DOI:10.1002/anie.201402067

Reference yield: 69.0%

1-phenylvinyl cyclohexa-1,3-dienecarboxylate (1627214-58-7) → 7a-phenyl-3,3a,7,7a-tetrahydro-3,6-methanobenzofuran-2(6H)-one (1627214-42-9)

Guidance literature:

With 1,3-bis-(1,3,5-trimethylphenyl)imidazol-2-ylidene; In 1,2-dichloro-benzene; at 0 ℃; for 6h; Reagent/catalyst; Solvent; Temperature; Time; Catalytic behavior; Inert atmosphere; Reflux;

DOI:10.1002/anie.201402067

upstream raw materials:

cyclohexa-1,3-diene-1-carboxylic acid

1-styrenyloxytrimethylsilane

Downstream raw materials:

7a-phenyl-3,3a,7,7a-tetrahydro-3,6-methanobenzofuran-2(6H)-one