2,3-DIHYDROBENZOIC ACID

Base Information

• Chemical Name: 2,3-DIHYDROBENZOIC ACID
• CAS No.: 2206-65-7
• Molecular Formula: C7H8O2
• Molecular Weight: 124.139
• Mol file: 2206-65-7.mol

Synonyms:Δ1.3-Dihydrobenzoesaeure;2,3-DIHYDROBENZOIC ACID;Cyclohexadien-(1,3)-carbonsaeure-(1);1,3-cyclohexadienoic acid;cyclohexa-1,3-dienecarboxylic acid;Cyclohexa-1,3-diencarbonsaeure;

Chemical Property of 2,3-DIHYDROBENZOIC ACID

Chemical Property:

• Boiling Point: 129 °C (4 mmHg)
• PSA: 37.30000
• LogP: 1.34740

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3-DIHYDROBENZOIC ACID

There total 9 articles about 2,3-DIHYDROBENZOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

methyl cyclohexa-1,3-diene-1-carboxylate (30810-15-2) → cyclohexa-1,3-diene-1-carboxylic acid (2206-65-7)

Guidance literature:

at 5 - 10 ℃; for 2h; alkaline hydrolysis;

Reference yield:

salicylic acid (69-72-7,25496-36-0,8052-31-1) → cyclohexa-1,4-diene-1-carboxylic acid (4315-35-9) + cyclohexa-1,3-diene-1-carboxylic acid (2206-65-7) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9)

Guidance literature:

With pyridine N-oxide; 1-Benzyl-1,4-dihydronicotinamide; In N,N-dimethyl-formamide; at 24.85 ℃; Further Variations:; Reagents; Solvents; Product distribution; Irradiation;

DOI:10.1039/b509447j

Reference yield:

water (7732-18-5) + 3-carboxy-tri-N-methyl-anilinium betaine (33192-03-9) → cyclohexa-1,3-diene-1-carboxylic acid (2206-65-7) + trimethylamine (75-50-3)

Guidance literature:

upstream raw materials:

1-acetoxybuta-1,3-diene

acrylic acid

methyl cyclohexa-1,3-diene-1-carboxylate

ethyl 1,3-cyclohexadiene-1-carboxylate

Downstream raw materials:

cyclohexa-1,3-dienecarboxamide

cyclohexene-1-carboxylic acid

4-benzyl-3-(4-methoxy-benzyl)-6-methyl-2-oxo-3-aza-tricyclo[5.2.2.0^1,5]undec-8-ene-6-carboxylic acid ethyl ester

cyclohexa-1,3-dienecarboxylic acid chloride