4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide

Base Information

• Chemical Name: 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide
• CAS No.: 1338062-05-7
• Molecular Formula: C₁₆H₁₈INO₃S
• Molecular Weight: 431.294
• Mol file: 1338062-05-7.mol

Synonyms:4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide

Chemical Property of 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide

There total 3 articles about 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

(2-propoxyphenyl)-λ3-iodanediyl diacetate (1338061-99-6) + toluene-4-sulfonamide (70-55-3) → 4-methyl-N-[(2-propoxyphenyl)-λ3-iodanylidene]benzenesulfonamide (1338062-05-7)

Guidance literature:

With potassium hydroxide; In methanol; Inert atmosphere;

DOI:10.1002/adsc.201700934

Reference yield:

2-Iodophenol (533-58-4) → 4-methyl-N-[(2-propoxyphenyl)-λ3-iodanylidene]benzenesulfonamide (1338062-05-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 3 h / 50 °C / Inert atmosphere

2.1: dihydrogen peroxide / water / 40 °C / Inert atmosphere

2.2: 8 h / 45 °C / Inert atmosphere

3.1: potassium hydroxide / methanol / 3 h / 0 - 20 °C / Inert atmosphere

With dihydrogen peroxide; potassium carbonate; potassium hydroxide; In methanol; water; N,N-dimethyl-formamide;

DOI:10.1002/chem.201102265

Reference yield:

1-iodo-2-propoxybenzene (857825-61-7) → 4-methyl-N-[(2-propoxyphenyl)-λ3-iodanylidene]benzenesulfonamide (1338062-05-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dihydrogen peroxide / water / 40 °C / Inert atmosphere

1.2: 8 h / 45 °C / Inert atmosphere

2.1: potassium hydroxide / methanol / 3 h / 0 - 20 °C / Inert atmosphere

With dihydrogen peroxide; potassium hydroxide; In methanol; water;

DOI:10.1002/chem.201102265

upstream raw materials:

(2-propoxyphenyl)-λ³-iodanediyl diacetate

toluene-4-sulfonamide

2-Iodophenol

1-iodo-2-propoxybenzene

Downstream raw materials:

1,1,2,3,4,5-hexahydro-1-<<(4-methylphenyl)sulfonyl>imino>tiophene 1-oxide

N-(p-tolylsulfonyl)-2-phenylaziridine

N-(p-toluenesulfonyl)-3-azatricyclo[3.2.1.0^2,4exo] octane

9-(toluene-4-sulfonyl)-9-aza-bicyclo[6.1.0]nonane