[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

Base Information

Chemical Name:[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester
CAS No.:366804-13-9
Molecular Formula:C₁₆H₁₆ClN₇O₇
Molecular Weight:453.799
Hs Code.:

Synonyms:[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

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Chemical Property of [(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

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Technology Process of [(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

There total 4 articles about [(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 4755-77-5
Ethyl oxalyl chloride

: 366804-11-7
C₁₂H₁₂ClN₇O₄

: 366804-13-9
[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

Guidance literature:: In toluene; Heating;
DOI:10.1021/jm010862q

Reference yield:

: 6641-64-1
4,5-dichloro-2-nitroaniline

: 366804-13-9
[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 89 percent / KOH / dimethylformamide / 6 h / 100 °C

2.1: H₂SO₄; aq. NaNO₂ / 0.25 h / 0 °C

2.2: aq. NaBF₄ / 0.5 h / 0 °C

2.3: 41 percent / methanol / 3 h / 20 °C

3.1: 77 percent / NH₃ / dioxane / 20 °C

4.1: 82 percent / toluene / Heating

With potassium hydroxide; sulfuric acid; ammonia; sodium nitrite; In 1,4-dioxane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jm010862q

Reference yield:

: 366804-07-1
4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenylamine

: 366804-13-9
[(4-chloro-2-nitro-5-[1,2,4]triazol-1-yl-phenyl)-hydrazono]-(ethoxyoxalyl-amino)-acetic acid ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: H₂SO₄; aq. NaNO₂ / 0.25 h / 0 °C

1.2: aq. NaBF₄ / 0.5 h / 0 °C

1.3: 41 percent / methanol / 3 h / 20 °C

2.1: 77 percent / NH₃ / dioxane / 20 °C

3.1: 82 percent / toluene / Heating

With sulfuric acid; ammonia; sodium nitrite; In 1,4-dioxane; toluene;
DOI:10.1021/jm010862q