{2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)

Base Information

Chemical Name:{2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)
CAS No.:1095192-63-4
Molecular Formula:C₅₀H₃₉BCuN₄O₂
Molecular Weight:802.242
Hs Code.:

Synonyms:{2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)

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Chemical Property of {2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)

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Technology Process of {2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)

There total 2 articles about {2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 71147-56-3
C₄₄H₂₇BrCuN₄

: 73183-34-3
bis(pinacol)diborane

: 1095192-63-4
{2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato}-copper(II)

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In water; toluene; at 110 ℃; for 4h; Inert atmosphere;
DOI:10.1021/ja8055886

Reference yield: 53.0%

: 71147-56-3
Cu(2+)-bromo-α,β,γ,δ-tetraphenylporphine

: 73183-34-3
bis(pinacol)diborane

: 1095192-63-4
(2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato)-copper(II)

Guidance literature:: With potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In water; toluene; (Ar); bromoporphirine, bis(pinacolato)diboron, palladium complex and CH3COOK were refluxed in toluene and water at 110°C for 4 h; CH2Cl2 was added, washed with water and satd. aq. soln. of NH4Cl, organic layer dried over MgSO4, evapd. in vac., column chromy. (silica gel, petroleum ether/CH2Cl2, 5:1 to 0:1, v/v);
DOI:10.1021/ja8055886

Reference yield: 33.0%

: 1095192-56-5
(2-bromo-5,10,15,20-tetraphenylporphyrinato)palladium(II)

: 1095192-63-4
(2-(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-5,10,15,20-tetraphenylporphyrinato)-copper(II)

: 1095192-73-6,1095669-92-3,1095669-93-4
((C₆H₅)4C₂₀H₇N₄Pd)((C₆H₅)4C₂₀H₇N₄Cu)

Guidance literature:: With barium dihydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; toluene; (Ar); toluene and water were added to mixture of boronic ester, bromoporphyrin and Ba(OH)2*8H2O, Pd(PPh3)4 was added, refluxed for 18 h with stirring; CH2Cl2 and H2O were added, aq. phase was extd. with CH2Cl2, combined organic phase was washed with water and satd. aq. soln. of NH4Cl, organic layer dried over MgSO4, evapd. in vac., column chromy. (silica gel, petroleum ether/CH2Cl2, 4:1 to 0:1, v/v);
DOI:10.1021/ja8055886