5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

Base Information

Chemical Name:5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)
CAS No.:1374751-55-9
Molecular Formula:C₆₉H₄₈
Molecular Weight:877.14
Hs Code.:

Synonyms:5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

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Chemical Property of 5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

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Technology Process of 5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

There total 2 articles about 5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1374751-54-8
1,3,5-tri(3′-mesitylbiphen-2-yl)benzene

: 1374751-55-9
5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

Guidance literature:: With iron(III) chloride; In nitromethane; ethanol; dichloromethane; at 25 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol300743f

Reference yield:

: 1374751-53-7
1,3,5-tri(3′-chlorobiphen-2-yl)benzene

: 1374751-55-9
5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

Guidance literature:: Multi-step reaction with 2 steps

1: bis(acetylacetonate)nickel(II); magnesium; lithium chloride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride / tetrahydrofuran / 24 h / 60 °C / Inert atmosphere

2: iron(III) chloride / nitromethane; ethanol; dichloromethane / 3 h / 25 °C / Inert atmosphere

With iron(III) chloride; bis(acetylacetonate)nickel(II); magnesium; lithium chloride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; In tetrahydrofuran; nitromethane; ethanol; dichloromethane; 1: Kumada coupling reaction / 2: Scholl reaction;
DOI:10.1021/ol300743f

Reference yield: 73.0%

: 1374751-55-9
5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,8,14-triyltris(trifluoromethanesulfonate)

: 73183-34-3
bis(pinacol)diborane

: 1374751-56-0
2,8,14-triboryl-5,11,17-trimesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In tert-butyl methyl ether; at 60 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ol300743f