2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

Base Information

• Chemical Name: 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• CAS No.: 1523440-95-0
• Molecular Formula: C₁₈H₂₂BNO₂
• Molecular Weight: 295.189
• Mol file: 1523440-95-0.mol

Synonyms:2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

Chemical Property of 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

There total 8 articles about 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-diphenylbenzamide (4051-56-3) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → N,N-diphenylbenzylamine (606-87-1) + 2-(benzyloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (95843-98-4) + 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (1523440-95-0)

Guidance literature:

With La(CH₂C₆H₄NMe₂-o)₃; In benzene-d6; at 80 ℃; for 24h; Glovebox; Inert atmosphere;

DOI:10.1039/d1nj04996h

Reference yield:

N,N-diphenylacetamide (519-87-9) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (1523440-95-0)

Guidance literature:

With triethyl borane; potassium hydroxide; In tetrahydrofuran; at 25 ℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.0c03033

Reference yield:

N,N-diphenylpropionamide (20619-23-2) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 2-(4-(diphenylamino)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) (1523440-95-0)

Guidance literature:

With triethyl borane; potassium hydroxide; In tetrahydrofuran; at 100 ℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.0c03033

upstream raw materials:

diphenylamine

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

N,N-diphenylacetamide

Downstream raw materials:

(Ru[(4,4'-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(N,N-diphenyl-4-aminophenyl)-2,2'-bipyridine)(NCS)₂])

4,4'-bis(N,N-diphenyl-4-aminophenyl)-2,2'-bipyridine

diphenylamine

1-(diphenylamino)propan-2-ol