Technology Process of C6H10O2C7H6SiC3H9CN
There total 1 articles about C6H10O2C7H6SiC3H9CN which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
titanium(IV) isopropylate;
In
dichloromethane;
at -20 ℃;
for 14h;
Title compound not separated from byproducts.;
DOI:10.1021/ol071024e
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: AcOH; HCl / 8 h / 20 °C
2.1: i-PrMgCl / tetrahydrofuran; diethyl ether / 1 h / -20 - 0 °C
3.1: Ac2O; AcOH / 16 h / 20 °C
4.1: t-BuLi / diethyl ether; pentane / 0.33 h / -78 - -40 °C
4.2: 72 mg / diethyl ether; pentane / 0.33 h / -78 °C
With
hydrogenchloride; tert.-butyl lithium; isopropylmagnesium chloride; acetic anhydride; acetic acid;
In
tetrahydrofuran; diethyl ether; pentane;
DOI:10.1021/ol071024e
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: AcOH; HCl / 8 h / 20 °C
2.1: i-PrMgCl / tetrahydrofuran; diethyl ether / 1 h / -20 - 0 °C
3.1: Ac2O; AcOH / 16 h / 20 °C
4.1: t-BuLi / diethyl ether; pentane / 0.33 h / -78 - -40 °C
4.2: 72 mg / diethyl ether; pentane / 0.33 h / -78 °C
5.1: 87 percent / LiI; LiAlH4 / diethyl ether / 0.33 h / -100 °C
6.1: 91 percent / Et3N; DMAP / CH2Cl2 / 3.5 h / 0 - 20 °C
With
hydrogenchloride; dmap; lithium aluminium tetrahydride; tert.-butyl lithium; isopropylmagnesium chloride; acetic anhydride; acetic acid; triethylamine; lithium iodide;
In
tetrahydrofuran; diethyl ether; dichloromethane; pentane;
DOI:10.1021/ol071024e
