dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

Base Information

Chemical Name:dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate
CAS No.:110077-61-7
Molecular Formula:C₄₀H₄₂I₂IrP₂*F₆Sb
Molecular Weight:1266.49
Hs Code.:

Synonyms:dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

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Chemical Property of dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

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Technology Process of dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

There total 1 articles about dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 91410-27-4
{Ir(COD)(PPh₃)2}SbF₆

: 75-03-6
ethyl iodide

: 110077-61-7
dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

Guidance literature:: With hydrogen; In dichloromethane; EtI was added to a CH2Cl2 soln. of Ir-complex at 0°C under N2 in the dark, N2 was replaced by an H2 atmosphere, mixt. stirred for 30 min; Et2O and pentane were added under H2 atmosphere, ppt. was filtered, washed with Et2O, dried in vacuo, recrystd. from CH2Cl2-Et2O-pentane, washed with pentane, dried in vacuo;
DOI:10.1021/om00153a035

Reference yield:

: 110077-61-7
dihydridobis(triphenylphosphine)bis(iodoethane)iridium(III) hexafluoroantimonate

: 110077-70-8
bis(μ-iodo)diethyltetrakis(triphenylphosphine)diiridium(III) bis(hexafluoroantimonate)

Guidance literature:: With t-BuCH=CH₂; In dichloromethane; stirred in CH2Cl2 at 20°C for 10 h under inert atmosphere (N2 or argon); Et2O was added, ppt. was filtered, washed with Et2O, dried in vacuo, recrystd. from CH2Cl2-Et2O;
DOI:10.1021/om00153a035