Lithium tert-butylcyclopentadienide

Base Information

Chemical Name:Lithium tert-butylcyclopentadienide
CAS No.:50356-03-1
Molecular Formula:C9H13 Li
Molecular Weight:128.143
Hs Code.:2902199090
European Community (EC) Number:684-543-4
Mol file:50356-03-1.mol

Synonyms:LITHIUM TERT-BUTYLCYCLOPENTADIENIDE;50356-03-1;tert-Butylcyclopentadienyl-lithium;Lithium t-butylcyclopentadienide;t-butylcyclopentadienyl lithium;t-butylcyclopentadienyl-lithium;JPXWDGHNZTWBHY-UHFFFAOYSA-N;UROXGIMUMKPQGM-UHFFFAOYSA-N;MFCD02093630;AKOS006229282;lithium;5-tert-butylcyclopenta-1,3-diene

Suppliers and Price of Lithium tert-butylcyclopentadienide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
LITHIUM TERT-BUTYLCYCLOPENTADIENIDE 95.00%
5MG
$ 498.42

Total 5 raw suppliers

Chemical Property of Lithium tert-butylcyclopentadienide

Chemical Property:

Melting Point:273-277 °C(lit.)
Flash Point:63 °F
PSA：0.00000
LogP:2.86650
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:128.11772885
Heavy Atom Count:10
Complexity:85.4

Purity/Quality:

98%Min ^*data from raw suppliers

LITHIUM TERT-BUTYLCYCLOPENTADIENIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): F,C
Hazard Codes:F,C
Statements: 11-14-34
Safety Statements: 16-26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[Li+].CC(C)(C)[C-]1C=CC=C1

Technology Process of Lithium tert-butylcyclopentadienide

There total 1 articles about Lithium tert-butylcyclopentadienide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 2175-91-9
6,6'-dimethyl fulvene

: 917-54-4
methyllithium

: 50356-03-1
Lithium tert-butylcyclopentadienide

Guidance literature:: In diethyl ether; at 0 - 20 ℃; for 12h; Inert atmosphere; Schlenk technique;
DOI:10.1002/ejic.201600502

Reference yield: 96.0%

: 436-59-9
dimesitylfluoroborane

: 50356-03-1
Lithium tert-butylcyclopentadienide

: lithium 1-dimesitylboryl-3-tert-butylcyclopentadienide

Guidance literature:: dimesitylfluoroborane; Lithium tert-butylcyclopentadienide; In 1,2-dimethoxyethane; for 15h;

With methyllithium; In 1,2-dimethoxyethane; diethyl ether; at -40 - 20 ℃; for 24h;
DOI:10.1021/acs.inorgchem.6b02510

Reference yield: 95.0%

: 36140-19-9
dicyclohexylboron chloride

: 50356-03-1
Lithium tert-butylcyclopentadienide

: lithium 1-dicyclohexylboryl-3-tert-butylcyclopentadienide

Guidance literature:: Lithium tert-butylcyclopentadienide; In hexane; at -50 ℃; for 1h;

dicyclohexylboron chloride; In hexane; at -30 - 20 ℃; for 9h;

With lithium hexamethyldisilazane; In hexane; at -60 ℃;
DOI:10.1021/acs.inorgchem.6b02510