dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Base Information

Chemical Name:dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate
CAS No.:1542560-25-7
Molecular Formula:C₂₆H₂₅ClO₅
Molecular Weight:452.935
Hs Code.:

Synonyms:dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Suppliers and Price of dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

There total 2 articles about dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1542558-89-3
dimethyl 2-(3-(4-chlorophenyl)prop-2-ynyl)-2-(3-methylbut-2-enyl)malonate

: 100-52-7
benzaldehyde

: 1542560-25-7
dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Guidance literature:: With tert.-butylhydroperoxide; Trimethylacetic acid; In acetonitrile; at 120 ℃; for 48h; Schlenk technique; Inert atmosphere;
DOI:10.1039/c3cc48339h

Reference yield:

: 106-39-8
bromochlorobenzene

: 107473-14-3
dimethyl 2-propargyl-2-prenylmalonate

: 1542560-25-7
dimethyl 4-benzoyl-7-chloro-9,9-dimethyl-9,9a-dihydro-1H-fluorene-2,2(3H)-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; isopropylamine / 20 °C

2: Trimethylacetic acid; tert.-butylhydroperoxide / acetonitrile / 48 h / 120 °C / Schlenk technique; Inert atmosphere

With tert.-butylhydroperoxide; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; isopropylamine; Trimethylacetic acid; In acetonitrile;
DOI:10.1039/c3cc48339h