Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

Base Information

Chemical Name:Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester
CAS No.:137918-62-8
Molecular Formula:C₂₀H₂₈O₇
Molecular Weight:380.438
Hs Code.:

Synonyms:Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

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Chemical Property of Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

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Technology Process of Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

There total 2 articles about Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-24-7
acetic anhydride

: 137918-61-7
(2S,4aR,6S,8R,8aR)-6,8-Dimethoxy-7,7-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

: 137918-62-8
Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

Guidance literature:: With lithium aluminium tetrahydride; aluminium trichloride; boron trifluoride diethyl etherate; Multistep reaction; 1.) Et₂O, CH₂Cl₂, reflux, 2.) RT;
DOI:10.1021/ja00025a056

Reference yield:

: 108-24-7
acetic anhydride

: 100-39-0
benzyl bromide

: 137918-61-7
(2S,4aR,6S,8R,8aR)-6,8-Dimethoxy-7,7-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

: 137918-62-8
Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

Guidance literature:: Multistep reaction;
DOI:10.1021/ja00025a056

Reference yield: 93.0%

: 137918-62-8
Acetic acid (2R,4R,5R,6R)-6-acetoxymethyl-5-benzyloxy-4-methoxy-3,3-dimethyl-tetrahydro-pyran-2-yl ester

: 762-72-1
allyl-trimethyl-silane

: 137918-63-9
Acetic acid (2R,3R,4R,6R)-6-allyl-3-benzyloxy-4-methoxy-5,5-dimethyl-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; In acetonitrile; at 0 ℃;
DOI:10.1021/ja00025a056