(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

Base Information

Chemical Name:(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole
CAS No.:127254-96-0
Molecular Formula:C₃₄H₂₈N₂S₂
Molecular Weight:528.742
Hs Code.:

Synonyms:(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

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Chemical Property of (6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

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Technology Process of (6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

There total 8 articles about (6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 127229-86-1,127305-93-5
(6α,6aα,12α,12aβ)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethylpentaleno<2,1-b:5,4-b'>diindole-6,12-diol

: 108-98-5
thiophenol

: 127254-96-0
(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

Guidance literature:: With zinc(II) iodide; In dichloromethane; for 3.5h; Ambient temperature;
DOI:10.1021/jo00299a031

Reference yield:

: 51716-63-3
cis-bicyclo[3. 3. 0]octane-3,7-dione

: 127254-96-0
(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

Guidance literature:: Multi-step reaction with 4 steps

1: 50 percent

2: 56 percent / SeO₂ / dioxane / 48 h / Heating

3: 95 percent / DIBAL / CH₂Cl₂ / -78 deg C to RT

4: 79 percent / ZnI₂ / CH₂Cl₂

With selenium(IV) oxide; diisobutylaluminium hydride; zinc(II) iodide; In 1,4-dioxane; dichloromethane;
DOI:10.1016/S0040-4020(01)80896-6

Reference yield:

: 100-63-0
phenylhydrazine

: 127254-96-0
(6α,6aα,12α,12aα)-5,6,6a,11,12,12a-Hexahydro-5,11-dimethyl-6,12-bis(phenylthio)pentaleno<2,1-b:5,4-b'>diindole

Guidance literature:: Multi-step reaction with 5 steps

1: 20 percent / HCl / ethanol / Δ

2: 90 percent / NaH / tetrahydrofuran

3: 56 percent / SeO₂ / dioxane / 48 h / Heating

4: 95 percent / DIBAL / CH₂Cl₂ / -78 deg C to RT

5: 79 percent / ZnI₂ / CH₂Cl₂

With selenium(IV) oxide; sodium hydride; diisobutylaluminium hydride; zinc(II) iodide; hydrogenchloride; In tetrahydrofuran; 1,4-dioxane; ethanol; dichloromethane;
DOI:10.1016/S0040-4020(01)80896-6