Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

Base Information

Chemical Name:Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester
CAS No.:165961-01-3
Molecular Formula:C₂₈H₅₂O₆SSi
Molecular Weight:544.869
Hs Code.:

Synonyms:Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

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Chemical Property of Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

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Technology Process of Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

There total 5 articles about Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 98-59-9
p-toluenesulfonyl chloride

: 165961-00-2
(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

: 165961-01-3
Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

Guidance literature:: With pyridine; at -20 ℃; for 41h;
DOI:10.1021/jo00119a019

Reference yield:

: 165960-98-5
(R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol

: 165961-01-3
Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / Et₃N, imidazole / CH₂Cl₂ / 18 h / Ambient temperature

2: 99 percent / Li, liq. NH₃ / diethyl ether / 1.) -78 deg C, 30 min, 2.) room temp., 3 h

3: 97 percent / pyridine / 41 h / -20 °C

With pyridine; 1H-imidazole; ammonia; lithium; triethylamine; In diethyl ether; dichloromethane;
DOI:10.1021/jo00119a019

Reference yield:

: 165960-97-4
((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene

: 165961-01-3
Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) BH₃*THF, 2.) aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, room temp., 12 h, 2.) room temp., 1 h

2: 99 percent / Et₃N, imidazole / CH₂Cl₂ / 18 h / Ambient temperature

3: 99 percent / Li, liq. NH₃ / diethyl ether / 1.) -78 deg C, 30 min, 2.) room temp., 3 h

4: 97 percent / pyridine / 41 h / -20 °C

With pyridine; 1H-imidazole; sodium hydroxide; borane-THF; ammonia; dihydrogen peroxide; lithium; triethylamine; In diethyl ether; dichloromethane;
DOI:10.1021/jo00119a019