tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

Base Information

Chemical Name:tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane
CAS No.:165961-02-4
Molecular Formula:C₂₇H₅₀O₃SSi
Molecular Weight:482.844
Hs Code.:

Synonyms:tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

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Chemical Property of tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

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Technology Process of tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

There total 6 articles about tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 108-98-5
thiophenol

: 165961-01-3
Toluene-4-sulfonic acid (R)-13-(tert-butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecyl ester

: 165961-02-4
tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

Guidance literature:: With sodium hydride; In tetrahydrofuran; 1.) 30 min, 2.) room temp., 2 h;
DOI:10.1021/jo00119a019

Reference yield:

: 165961-00-2
(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

: 165961-02-4
tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / pyridine / 41 h / -20 °C

2: 92 percent / NaH / tetrahydrofuran / 1.) 30 min, 2.) room temp., 2 h

With pyridine; sodium hydride; In tetrahydrofuran;
DOI:10.1021/jo00119a019

Reference yield:

: 165960-98-5
(R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol

: 165961-02-4
tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / Et₃N, imidazole / CH₂Cl₂ / 18 h / Ambient temperature

2: 99 percent / Li, liq. NH₃ / diethyl ether / 1.) -78 deg C, 30 min, 2.) room temp., 3 h

3: 97 percent / pyridine / 41 h / -20 °C

4: 92 percent / NaH / tetrahydrofuran / 1.) 30 min, 2.) room temp., 2 h

With pyridine; 1H-imidazole; ammonia; lithium; sodium hydride; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo00119a019