1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

Base Information

Chemical Name:1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine
CAS No.:1421692-14-9
Molecular Formula:C₂₂H₂₉NSi
Molecular Weight:335.564
Hs Code.:

Synonyms:1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

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Technology Process of 1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

There total 2 articles about 1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 92962-30-6
2-methyl-3,3-diphenylpropanenitrile

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1421692-14-9
1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

Guidance literature:: 2-methyl-3,3-diphenylpropanenitrile; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h; Inert atmosphere;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ja312141b

Reference yield:

: 2286-54-6
3,3-diphenyl-propionitrile

: 1421692-14-9
1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 1 h / -78 °C / Inert atmosphere

2.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

2.2: 12 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane;
DOI:10.1021/ja312141b

Reference yield:

: 1421692-14-9
1-tert-butyl-1,1-dimethyl-N-(2-methyl-3,3-diphenylprop-1-en-1-ylidene)silanamine

: 62907-42-0
(S)-2-methyl-3,3-diphenylpropanenitrile

: 28098-85-3
(R)-2-methyl-3,3-diphenylpropanenitrile

Guidance literature:: With (S)-3,3'-bis(2,4,6-tri-iso-propylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate; In methanol; toluene; pentane; at -78 - 20 ℃; for 12h; Overall yield = 90 %; Overall yield = 40 mg; enantioselective reaction;
DOI:10.1021/ja312141b