p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

Base Information

Chemical Name:p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside
CAS No.:1320281-36-4
Molecular Formula:C₂₇H₂₇N₃O₄S
Molecular Weight:489.595
Hs Code.:

Synonyms:p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

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Chemical Property of p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

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Technology Process of p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

There total 10 articles about p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1125-88-8
benzaldehyde dimethyl acetal

: 1320281-42-2
p-tolyl 2-azido-3-O-benzyl-2-deoxy-1-thio-α-D-mannopyranoside

: 1320281-36-4
p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

Guidance literature:: With toluene-4-sulfonic acid; In acetonitrile; for 48h;
DOI:10.1021/ol2016862

Reference yield:

: C₂₀H₂₁N₃O₄S

: 100-39-0
benzyl bromide

: 1320281-36-4
p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

: tolyl 2-azido-4,6-O-benzylidene-3-O-benzyl-2-deoxy-1-thio-α-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1002/asia.200900765

Reference yield:

: 1320281-35-3
p-tolyl 4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-1-thio-α-D-mannopyranoside

: 1320281-36-4
p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: methanol; sodium methylate / dichloromethane / 48 h

2: toluene-4-sulfonic acid / acetonitrile / 48 h

With methanol; sodium methylate; toluene-4-sulfonic acid; In dichloromethane; acetonitrile;
DOI:10.1021/ol2016862