ferrocene methyl triphenylphosphine hydrobromate

Base Information

• Chemical Name: ferrocene methyl triphenylphosphine hydrobromate
• CAS No.: 223134-54-1
• Molecular Formula: Br*C₂₉H₂₆FeP
• Molecular Weight: 541.25
• Mol file: 223134-54-1.mol

Synonyms:ferrocene methyl triphenylphosphine hydrobromate

Chemical Property of ferrocene methyl triphenylphosphine hydrobromate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of ferrocene methyl triphenylphosphine hydrobromate

There total 2 articles about ferrocene methyl triphenylphosphine hydrobromate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-ferrocenylmethanol (1273-86-5) + triphenylphosphine hydrobromide (6399-81-1) → ferrocene methyl triphenylphosphine hydrobromate (223134-54-1)

Guidance literature:

In toluene; mixt. of ferrocenemethanol, PPh3*HBr and toluene refluxed for 30 min (azeotropic condensate sepd. in Dean-Stark trap); cooled; filtered; ppt. washed with ether, dried; filtrate concd. to obtain additional portion, extd. with H2O, aq. layer washed with ether, extd. with CHCl3, solvent evapd.;

DOI:10.1039/b506992k

Reference yield:

ferrocenecarboxaldehyde (12093-10-6) + triphenylphosphine hydrobromide (6399-81-1) → ferrocene methyl triphenylphosphine hydrobromate (223134-54-1)

Guidance literature:

ferrocenecarboxaldehyde; With sodium tetrahydroborate;

triphenylphosphine hydrobromide;

DOI:10.1021/acs.inorgchem.9b02227

Reference yield: 75.0%

ferrocene methyl triphenylphosphine hydrobromate (223134-54-1) + terephthalaldehyde, (623-27-8) → 4‐(2‐ferrocenylvinyl)benzaldehyde (123931-08-8,72022-45-8,98243-45-9)

Guidance literature:

With potassium t-butoxide; In tetrahydrofuran; refluxing Fe-complex with 4 equiv. of aldehyde for 4 h; addn. of H2O, extn. into Et2O, washing (brine), drying (MgSO4), evapn., chromy. (SiO2, CH2Cl2/hexane=1:4);

DOI:10.1016/S0022-328X(98)01009-2

upstream raw materials:

1-ferrocenylmethanol

triphenylphosphine hydrobromide

ferrocenecarboxaldehyde

Downstream raw materials:

4‐(2‐ferrocenylvinyl)benzaldehyde