N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride

Base Information

• Chemical Name: N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride
• CAS No.: 1264737-51-0
• Molecular Formula: C₁₄H₁₄FNO₃S₂
• Molecular Weight: 327.4
• Mol file: 1264737-51-0.mol

Synonyms:N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride

Chemical Property of N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride

There total 3 articles about N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl chloride (108875-13-4) → N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride (1264737-51-0)

Guidance literature:

With potassium fluoride; 18-crown-6 ether; In acetonitrile; at 21 ℃; for 16h; Inert atmosphere;

DOI:10.1021/ol103030w

Reference yield:

4-methylbenzenesulfinyl chloride (10439-23-3) → N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride (1264737-51-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / 21 - 85 °C

2: potassium fluoride; 18-crown-6 ether / acetonitrile / 16 h / 21 °C / Inert atmosphere

With potassium fluoride; 18-crown-6 ether; In toluene; acetonitrile;

DOI:10.1021/ol103030w

Reference yield:

sodium 4-methylbenzenesulfinate (824-79-3) → N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl fluoride (1264737-51-0)

Guidance literature:

Multi-step reaction with 3 steps

1: thionyl chloride

2: toluene / 21 - 85 °C

3: potassium fluoride; 18-crown-6 ether / acetonitrile / 16 h / 21 °C / Inert atmosphere

With potassium fluoride; thionyl chloride; 18-crown-6 ether; In toluene; acetonitrile;

DOI:10.1021/ol103030w

upstream raw materials:

4-methylbenzenesulfinyl chloride

N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl chloride

sodium 4-methylbenzenesulfinate

Downstream raw materials:

N-(4-methylbenzenesulphonyl)-4-methylbenzene-trifluoromethyl sulfoximine