Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Base Information

Chemical Name:Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester
CAS No.:143570-33-6
Molecular Formula:C₁₄H₂₉O₈PS
Molecular Weight:388.419
Hs Code.:

Synonyms:Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

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Chemical Property of Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

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Technology Process of Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

There total 4 articles about Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 143570-28-9
Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl) ester

: 143570-33-6
Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: With boron trifluoride diethyl etherate; ethanethiol; In chloroform;
DOI:10.1016/S0040-4039(00)74812-X

Reference yield:

: 111-88-6
Octanethiol

: 143570-33-6
Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1) n-BuLi / 1) THF, 0 deg C, 30 min, 2) room temp., 1 h

2: CH₂Cl₂ / 6 h / Ambient temperature

3: triisopropylbenzenesulfonyl chloride (TPSCl), NEt₃, pyridine / 24 h / Ambient temperature

4: 93 percent / BF₃*Et₂O, EtSH / CHCl₃

With pyridine; n-butyllithium; triisopropylbenzenesulfonyl chloride; boron trifluoride diethyl etherate; triethylamine; ethanethiol; In dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74812-X

Reference yield:

: 20195-14-6
O,O-diethyl S-n-octane phosphorothioate

: 143570-33-6
Thiophosphoric acid S-octyl ester O-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: CH₂Cl₂ / 6 h / Ambient temperature

2: triisopropylbenzenesulfonyl chloride (TPSCl), NEt₃, pyridine / 24 h / Ambient temperature

3: 93 percent / BF₃*Et₂O, EtSH / CHCl₃

With pyridine; triisopropylbenzenesulfonyl chloride; boron trifluoride diethyl etherate; triethylamine; ethanethiol; In dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74812-X