(3S)-3-hex-5-enoic acid

Base Information

Chemical Name:(3S)-3-hex-5-enoic acid
CAS No.:116627-58-8
Molecular Formula:C₂₂H₂₈O₃Si
Molecular Weight:368.548
Hs Code.:

(3S)-3-<t-butyl(diphenyl)silyloxy>hex-5-enoic acid

Synonyms:(3S)-3-hex-5-enoic acid

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Chemical Property of (3S)-3-hex-5-enoic acid

Chemical Property:

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Technology Process of (3S)-3-hex-5-enoic acid

There total 14 articles about (3S)-3-hex-5-enoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 116627-57-7
(S)-3-(tert-Butyl-diphenyl-silanyloxy)-hex-5-enoic acid propyl ester

: 116627-58-8
(3S)-3-hex-5-enoic acid

Guidance literature:: With sodium hydroxide; In ethanol; water; at 25 ℃;
DOI:10.1016/S0040-4039(00)86112-2

Reference yield:

: 542-05-2
acetonedicarboxylic acid

: 116627-58-8
(3S)-3-hex-5-enoic acid

Guidance literature:: Multi-step reaction with 9 steps

1: 85 percent / HCl gas / 0 °C

2: 91 percent / H₂ / Raney-Ni / propan-1-ol; triethylamine / 25 °C

3: H₂O / pig liver esterase (PLE) / 30 h / 0 °C / pH 7 (0.3 M aqueous KH₂PO₄ and 1N NaOH)

4: imidazol / CH₂Cl₂ / 0 °C

5: H₂O, Na₂CO₃ / 25 °C

6: BF₃-THF / 6 h / -20 - 0 °C

7: PCC, kieselguhr / CH₂Cl₂ / 25 °C

8: 93 percent / toluene / 2 h / -15 - 0 °C

9: 99 percent / NaOH / ethanol; H₂O / 25 °C

With 1H-imidazole; hydrogenchloride; sodium hydroxide; kieselguhr; boron trifluoride-tetrahydrofuran complex; water; hydrogen; sodium carbonate; pyridinium chlorochromate; pig liver esterase; nickel; In propan-1-ol; ethanol; dichloromethane; water; triethylamine; toluene;
DOI:10.1016/S0040-4039(00)86112-2

Reference yield:

: 116643-38-0
(3S)-3-tert-butyldiphenylsiloxyglutaric acid monopropyl ester

: 116627-58-8
(3S)-3-hex-5-enoic acid

Guidance literature:: Multi-step reaction with 4 steps

1: BF₃-THF / 6 h / -20 - 0 °C

2: PCC, kieselguhr / CH₂Cl₂ / 25 °C

3: 93 percent / toluene / 2 h / -15 - 0 °C

4: 99 percent / NaOH / ethanol; H₂O / 25 °C

With sodium hydroxide; kieselguhr; boron trifluoride-tetrahydrofuran complex; pyridinium chlorochromate; In ethanol; dichloromethane; water; toluene;
DOI:10.1016/S0040-4039(00)86112-2