CH₃OC₆H₅C₆H₅Mn(CO)3

Base Information

Chemical Name:CH₃OC₆H₅C₆H₅Mn(CO)3
CAS No.:81857-39-8
Molecular Formula:C₁₆H₁₃MnO₄
Molecular Weight:324.215
Hs Code.:

CH<sub>3</sub>OC<sub>6</sub>H<sub>5</sub>C<sub>6</sub>H<sub>5</sub>Mn(CO)3

Synonyms:CH₃OC₆H₅C₆H₅Mn(CO)3

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Chemical Property of CH₃OC₆H₅C₆H₅Mn(CO)3

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Technology Process of CH₃OC₆H₅C₆H₅Mn(CO)3

There total 2 articles about CH₃OC₆H₅C₆H₅Mn(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 57812-97-2
CH₃OC₆H₅Mn(CO)3

: 81857-39-8
CH₃OC₆H₅C₆H₅Mn(CO)3

Guidance literature:: With phenylmagnesium bromide; In tetrahydrofuran; addition of Grignard reagent to a stirred suspn. of complex at 0°C, stirred for 10 min; quenching with dilute HCl, warming to room temperature, filtration, evapn., extn. (ethyl ether), evapn.; elem. anal.;

Reference yield: 80.0%

: 89672-80-0
anisolemanganese tricarbonyl tetrafluoroborate

: 100-59-4
phenylmagnesium chloride

: 81857-39-8
(η5-2-methoxy-6-phenylcyclohexadienyl)Mn(CO)3

Guidance literature:: In not given; treatment of mangansese compd. with phenylmagnesium chloride;
DOI:10.1021/om200905p

Reference yield: 96.0%

: 811-98-3
d⁽⁴⁾-methanol

: 81857-39-8
(η5-2-methoxy-6-phenylcyclohexadienyl)Mn(CO)3

: 1010731-51-7
(η5-2-methoxy-3-D-6-phenylcyclohexadienyl)Mn(CO)3

Guidance literature:: With n-BuLi; N,N,N',N'-tetramethylethylenediamine; In tetrahydrofuran; hexane; under N2; soln. of Mn complex and Me2NCH2CH2NMe2 in THF cooled to -78°C; soln. of n-BuLi in hexanes slowly added; stirred at -78°Cfor 1 h; CD3OD added; stirred at -78°C for 1 h; warmed to room t emp.; quenched by addition of H2O; extd. with Et2O; combined org. layers washed with satd. aq. NaCl; dried (MgSO4); concd. in vac.; purified by flash chromy. (silica gel);
DOI:10.1021/om7010529