Technology Process of C28H46O5
There total 5 articles about C28H46O5 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
osmium(VIII) oxide; 4-methylmorpholine N-oxide;
In
water; acetone; tert-butyl alcohol;
at 20 ℃;
for 25h;
Inert atmosphere;
Darkness;
DOI:10.1021/ol302820c
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: peracetic acid; acetic acid / 0 - 20 °C / Inert atmosphere
1.2: 20 °C / Inert atmosphere
2.1: dimethylsulfide borane complex / tetrahydrofuran / -15 - 20 °C / Inert atmosphere
3.1: dimethyl sulfoxide; oxalyl dichloride; triethylamine / dichloromethane / -78 - 20 °C / Inert atmosphere
4.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere
4.2: -78 - 20 °C / Inert atmosphere
5.1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / water; acetone; tert-butyl alcohol / 25 h / 20 °C / Inert atmosphere; Darkness
With
peracetic acid; osmium(VIII) oxide; oxalyl dichloride; dimethylsulfide borane complex; sodium hexamethyldisilazane; acetic acid; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine;
In
tetrahydrofuran; dichloromethane; water; acetone; tert-butyl alcohol;
3.1: |Swern Oxidation / 4.1: |Wittig Olefination;
DOI:10.1021/ol302820c
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: peracetic acid; acetic acid / 0 - 20 °C / Inert atmosphere
1.2: 20 °C / Inert atmosphere
2.1: dimethylsulfide borane complex / tetrahydrofuran / -15 - 20 °C / Inert atmosphere
3.1: dimethyl sulfoxide; oxalyl dichloride; triethylamine / dichloromethane / -78 - 20 °C / Inert atmosphere
4.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere
4.2: -78 - 20 °C / Inert atmosphere
5.1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / water; acetone; tert-butyl alcohol / 25 h / 20 °C / Inert atmosphere; Darkness
With
peracetic acid; osmium(VIII) oxide; oxalyl dichloride; dimethylsulfide borane complex; sodium hexamethyldisilazane; acetic acid; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine;
In
tetrahydrofuran; dichloromethane; water; acetone; tert-butyl alcohol;
3.1: |Swern Oxidation / 4.1: |Wittig Olefination;
DOI:10.1021/ol302820c