manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate

Base Information

• Chemical Name: manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate
• CAS No.: 356042-09-6
• Molecular Formula: C₃₇Br₈F₁₅MnN₄
• Molecular Weight: 1479.58
• Mol file: 356042-09-6.mol

Synonyms:manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate

Chemical Property of manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate

There total 2 articles about manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (262280-87-5) → 2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (356042-09-6)

Guidance literature:

With bromine; In methanol; at 20 ℃;

DOI:10.1021/ja1050296

Reference yield: 85.0%

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate (262280-87-5) + bromine (7726-95-6) → manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate (356042-09-6)

Guidance literature:

In methanol; stirred overnight; volatiles removed (vac.), recrystd. (ethanol/H2O);

DOI:10.1002/1521-3773(20010601)40:11<2132::AID-ANIE2132>3.0.CO;2-5

Reference yield: 86.0%

2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) (356042-09-6) → β-octabromo-meso-5,10,15-tris(pentafluorophenyl)corrole

Guidance literature:

With sulfuric acid; iron(II) chloride; at 40 ℃; for 2h;

DOI:10.1142/S1088424610002331

upstream raw materials:

manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate

bromine

5,10,15-tris(pentafluorophenyl)corrolato-manganese(III)

Downstream raw materials:

Mn(C₁₉Br₈N₄(C₆F₅)3)(N-2,4,6-Cl₃C₆H₂)

Mn(C₁₉Br₈N₄(C₆F₅)3)(N-2,4,6-(CH₃)3C₆H₂)

2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato gold(III)