DIIODOMETHANE-D2

Base Information

• Chemical Name: DIIODOMETHANE-D2
• CAS No.: 15729-58-5
• Molecular Formula: CD2 I2
• Molecular Weight: 269.82
• Mol file: 15729-58-5.mol

Synonyms:Dideuteriodiiodomethane;Dideuterodiiodomethane; Diiodomethane-d2; Methylene-d2 iodide

Chemical Property of DIIODOMETHANE-D2

Chemical Property:

• Boiling Point: 68 ºC15 mm Hg(lit.)
• Flash Point: >230 ºF
• PSA: 0.00000
• Density: 3.325 g/mL at 25 ºC(lit.)
• LogP: 1.81390

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diiodomethane-d2 99 atom % D, contains copper as stabilizer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C,Xn
• Statements: 34-36/37/38-22
• Safety Statements: 26-27-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Diiodomethane-d2 (CAS# 15729-58-5) is a useful isotopically labeled research compound. Used to prepare deuterated fulvene for retro-Diels-Alder studies.

Technology Process of DIIODOMETHANE-D2

There total 7 articles about DIIODOMETHANE-D2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

dichloromethane-d2 (1665-00-5) + methyl iodide (74-88-4) → diiodomethane-d2 (15729-58-5)

Guidance literature:

With aluminium trichloride; for 3h; Heating;

Reference yield: 7.2%

diiodomethane (75-11-6) → deuteriated methylene diiodide (2253-85-2) + diiodomethane-d2 (15729-58-5)

Guidance literature:

With water-d2; sodium; sodium iodide; In 1,4-dioxane; methanol;

DOI:10.1021/jo00327a003

Reference yield:

iodomethane-d3 (865-50-9) → methane (558-20-3) + diiodomethane-d2 (15729-58-5)

Guidance literature:

With silver; at -173.1 ℃; Product distribution; Irradiation; 248 nm photochemistry;

DOI:10.1021/j100044a032

upstream raw materials:

diiodomethane

iodoform

dichloromethane-d2

methyl iodide

Downstream raw materials:

methylene-d₂-bis(4-methylbenzenesulfonate)

1-bromo-2-(3,3-dideuterioallyl)benzene

trans-1,2-diphenylcyclopropane-3-D₂

Refernces

• 1、 Blanchard,Simmons. "". . p. 1337,1338. Retrieved 1964.
• 2、 Charette, Andre B.,Gagnon, Alexandre,Fournier, Jean-Francois. "First evidence for the formation of a geminal dizinc carbenoid: A highly stereoselective synthesis of 1,2,3-Substituted cyclopropanes". . p. 386 - 387. Retrieved 2007/10/03.
• 3、 Kopinke, Frank-Dieter,Zimmermann, Gerhard,Aust, Janette,Scherzer, Klaus. "Gas-Phase Pyrolysis of Phenylcyclopropane". . p. 721 - 726. Retrieved 2007/10/02.